葵花籽蛋白-黄原胶Pickering乳液的制备与性质OA
Preparation and Properties of Sunflower Seed Protein-Xanthan Gum Pickering Emulsion
为提高葵花籽蛋白的高值化利用,以葵花籽蛋白(Sunflower seed protein,SSP)和黄原胶(Xanthan gum,XG)作为原料,制备复合颗粒并用于稳定Pickering乳液.通过傅里叶变换红外光谱、接触角测量仪、扫描电镜对SSP-XG进行表征,探究SSP与XG质量比对SSP-XG颗粒特性的影响;以粒径、Zeta电位、乳化活性指数(Emulsifying activity index,EAI)和乳液稳定性指数(Emulsion stability index,ESI)为指标,分析不同SSP-XG质量比和油相体积分数对Pickering乳液微观结构、流变特性和稳定性的影响.结果表明:SSP与XG二者存在氢键、静电相互作用和疏水相互作用;XG的加入使SSP-XG表面更光滑且增大了接触角测量值.SSP与XG质量比为 5:1,油相体积分数为 70%的Pickering乳液粒径最小(6.65 μm),Zeta电位最大(28.82 mV),EAI和ESI最大(1.26 m2/g,154.81 min),液滴分布均匀,呈现良好的凝胶网络结构,具有良好的乳化性和稳定性,且在 4℃下储藏乳析指数更小,具有较高的pH稳定性、离子稳定性和加热稳定性;流变学剪切变稀的行为,表明该乳液属于非牛顿流体;激光共聚焦显微镜显示复合颗粒包围在油相液滴周边,形成了水包油(O/W)型乳液.本研究可为开发新型绿色食品级Pickering乳液提供有益参考.
In order to improve the high-value utilization of sunflower seed protein,composite particles were prepared using sunflower seed protein(SSP)and xanthan gum(XG)as raw materials and used to stabilize Pickering emulsions.SSP-XG was characterized using Fourier transform infrared spectroscopy,contact angle measurement,and scanning electron microscopy to investigate the effect of the mass ratio of SSP to XG on the properties of SSP-XG particles.Particle size,Zeta potential,emulsifying activity index(EAI),and emulsion stability index(ESI)as indicators,this study analyzed the effects of different SSP-XG mass ratios and oil phase volume fractions on the microstructure,rheological properties and stability of Pickering emulsions.The results showed that hydrogen bonds,electrostatic interactions,and hydrophobic interactions existed between SSP and XG.The addition of XG made the SSP-XG surface smoother and increased the contact angle measurement value.The mass of SSP to XG ratio was 5:1,and the Pickering emulsion with an oil phase volume fraction of 70%exhibited the smallest particle size(6.65 μm),the highest Zeta potential(28.82 mV),and the highest EAI and ESI(1.26 m2/g,154.81 min),the droplets were evenly distributed,forming a well developed gel network structure,and demonstrated excellent emulsification and stability.Additionally,it showed a lower emulsification index when stored at 4℃.They also had high pH,ionic stability and heat stability.The shear thinning behavior of rheology indicated that the emulsion was a non-Newtonian fluid.Laser confocal microscopy showed composite particles surrounding oil phase droplets,forming an oil-in-water(O/W)type emulsion.This study provides useful reference for the development of new green food-grade Pickering emulsions.
公伶俐;楚晨俐;杨晗;努尔则巴·努尔麦麦提;布买丽亚木·买买提吐逊;孔令明
新疆农业大学食品科学与药学学院,新疆 乌鲁木齐 830052新疆农业大学食品科学与药学学院,新疆 乌鲁木齐 830052新疆农业大学食品科学与药学学院,新疆 乌鲁木齐 830052新疆农业大学食品科学与药学学院,新疆 乌鲁木齐 830052新疆农业大学食品科学与药学学院,新疆 乌鲁木齐 830052新疆农业大学食品科学与药学学院,新疆 乌鲁木齐 830052
轻工纺织
葵花籽蛋白黄原胶Pickering乳液复合颗粒性质
sunflower seed proteinxanthan gumPickering emulsioncomposite particleproperty
《食品工业科技》 2026 (8)
109-121,13
新疆维吾尔自治区油料产业技术体系资助(XJARS-05-09)自治区农业农村发展创新与服务项目:葵花籽饼粕中蛋白资源高值化加工技术示范推广项目2025年度校级研究生教育创新计划项目(XJAUGRI2025077).
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