氧化钙对锆酸钡陶瓷型芯性能的影响OA
Effect of Calcium Oxide on Properties of Barium Zirconate Ceramic Core
陶瓷型芯是制备空心涡轮叶片的关键材料,其性能会影响叶片品质和成品率.目前,现有氧化硅和氧化铝陶瓷型芯已不能满足更高温度合金叶片的铸造需求,新体系陶瓷型芯的研究迫在眉睫.本研究制备了锆酸钡基型芯材料,探索了氧化钙含量及烧结温度对锆酸钡-氧化钙复合型芯结构、力学性能和腐蚀脱除性能的影响.结果表明,烧结温度一定时,随着氧化钙含量的增加,型芯烧结失重率也增加,气孔率先增加后降低,体积密度和抗弯强度则先降低后增加.烧结温度对型芯烧结失重率的影响较小,随着烧结温度的升高,气孔率整体呈减小趋势,体积密度和抗弯强度总体呈增大趋势.型芯脱除速率均随烧结温度的升高而降低,添加氧化钙也会降低脱除速率.通过综合分析,氧化钙添加量为10%、烧结温度为1 600℃时,锆酸钡-氧化钙复合型陶瓷型芯材料的性能较为优异,其烧结失重率为4.22%,气孔率为12.1%,体积密度为4.72 g/cm3,抗弯强度可达66.15 MPa.
Ceramic core is the key material of preparing hollow turbine blade,and its performance affects the quality and yield of the blade.At present,the existing silica and alumina ceramic cores cannot meet the requirements of casting alloy blades at higher temperatures,it is urgent to develop new system of ceramic cores.In this study,the ceramic cores based on barium zirconate were prepared,and the effects of calcium oxide content and sintering temperature on the structure,mechanical properties and leachability of the barium zirconate-calcium oxide composite cores were explored.The results show that,at a certain sintering temperature,with the increase of calcium oxide content,the core weight loss rate increases,the porosity first increases and then decreases,and the bulk density and the flexural strength first decrease and then increase.Sintering temperature has a relatively minor effect on the mass loss of the core,with the increase of sintering temperature,the porosity decreases,and the bulk density and the flexural strength increase.The core removal rate decreases with the increase of sintering temperature,and the addition of CaO can reduce the removal rate,too.Through comprehensive analysis,when the calcium oxide content is 10%and the sintering temperature is 1 600℃,the barium zirconate-calcium oxide composite ceramic core material exhibits relatively excellent properties,with sintering weight loss rate of 4.22%,porosity of 12.1%,bulk density of 4.72 g/cm3,and the flexural strength can reach 66.15 MPa.
张婷婷;王泽丽;张家琪;孙健新;秦胜建;秦国强;于刚;吴红亚;杨治刚
石家庄铁道大学材料科学与工程学院,超材料与微器件河北省工程研究中心,河北 石家庄 050043石家庄铁道大学材料科学与工程学院,超材料与微器件河北省工程研究中心,河北 石家庄 050043石家庄铁道大学材料科学与工程学院,超材料与微器件河北省工程研究中心,河北 石家庄 050043石家庄铁道大学材料科学与工程学院,超材料与微器件河北省工程研究中心,河北 石家庄 050043石家庄铁道大学材料科学与工程学院,超材料与微器件河北省工程研究中心,河北 石家庄 050043石家庄铁道大学材料科学与工程学院,超材料与微器件河北省工程研究中心,河北 石家庄 050043石家庄铁道大学材料科学与工程学院,超材料与微器件河北省工程研究中心,河北 石家庄 050043石家庄铁道大学材料科学与工程学院,超材料与微器件河北省工程研究中心,河北 石家庄 050043石家庄铁道大学材料科学与工程学院,超材料与微器件河北省工程研究中心,河北 石家庄 050043
化学化工
陶瓷型芯锆酸钡氧化钙烧结温度性能调控型芯脱除复合陶瓷
ceramic corebarium zirconatecalcium oxidesintering temperatureproperty regulationcore removalcomposite ceramic
《铸造》 2026 (10)
1113-1119,7
河北省自然科学基金项目(E2025210108)石家庄铁道大学基本科研业务费项目(ZQK202501).
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