首页|期刊导航|铸造|热压注双层壁陶瓷型芯用SiC增强水溶蜡型芯性能和水溶解行为

热压注双层壁陶瓷型芯用SiC增强水溶蜡型芯性能和水溶解行为OA

Properties and Water-Dissolution Behaviors of SiC-Reinforced Water-Soluble Wax Cores for Hot-Injection-Molded Double-Wall Ceramic Cores

中文摘要英文摘要

水溶性石蜡是热压注工艺制备新一代双层壁陶瓷型芯不可或缺的关键过渡材料,其力学性能、热稳定性及溶解效率是影响其工程化应用的关键问题.本研究以不同含量的SiC颗粒作为增强相制备水溶蜡型芯试样,系统研究了SiC含量对水溶蜡型芯力学性能、热稳定性及溶解行为的影响,并进一步考察了pH值和温度对水溶蜡型芯材料溶解行为的影响机制.结果表明,当SiC含量为0.9wt.%时,水溶蜡型芯的综合性能最优,其室温抗弯强度为13.5 MPa,较未强化型芯提高了12.5%;热变形率降至12%,较未强化型芯降幅达56.4%,显著改善了水溶蜡型芯的尺寸稳定性.然而,在pH=2的酸性溶液中,0.9wt.%SiC强化的水溶蜡型芯试样的溶解时间延长至17.5 min,较未强化型芯增加了34.6%;在强酸性(pH=1)环境下溶解时间缩短至16 min;当温度从15℃升至35℃时,溶解时间由15.8 min锐减至6.9 min,降幅达56.3%,表明升高温度和降低pH值可有效加速SiC强化水溶蜡型芯的溶出,可在保证型芯材料强度的同时实现高效脱除.

Water-soluble paraffin wax is a critical transitional material for fabricating next-generation double-wall ceramic cores using the hot-pressing injection process,and its mechanical properties,thermal stability,and dissolution behavior are key factors governing its engineering applicability.In this study,the water-soluble wax core specimens were prepared with varying SiC particle contents as the reinforcing phase,and the effects of SiC contents on the mechanical properties,thermal stability,and dissolution behavior of the water-soluble wax cores were systematically investigated.In addition,mechanisms underlying the effects of pH and temperature on the dissolution behaviors of the optimized water-soluble wax core materials were examined.The results show that the water-soluble wax core containing 0.9wt.%SiC exhibits the best overall performance,with a room-temperature flexural strength of 13.5 MPa,12.5%higher than that of the unreinforced core;and its thermal deformation ratio is decreased to 12%,representing a 56.4%reduction compared with that of the unreinforced core,and indicating significantly improved dimensional stability of the water-soluble wax core.However,in an acidic solution with pH=2,the dissolution time of the 0.9wt.%SiC-reinforced water-soluble wax core specimen increases to 17.5 min,34.6%longer than that of the unreinforced core;under strongly acidic conditions(pH=1),the dissolution time is decreased to 16 min;as the solution temperature increases from 15 ℃ to 35 ℃,the dissolution time is sharply decreased from 15.8 min to 6.9 min,corresponding to a reduction of 56.3%,indicating that increasing temperature and decreasing pH can effectively accelerate the dissolution of SiC-reinforced water-soluble wax cores,enabling efficient core removal while maintaining adequate mechanical strength.

李乔磊;张婷婷;李鑫;梁静静;周亦胄;李金国

中国科学院金属研究所,辽宁 沈阳 110016中国科学院金属研究所,辽宁 沈阳 110016中国航发北京航空材料研究院先进高温结构材料重点实验室,北京 100095中国科学院金属研究所,辽宁 沈阳 110016中国科学院金属研究所,辽宁 沈阳 110016中国科学院金属研究所,辽宁 沈阳 110016

矿业与冶金

水溶蜡陶瓷型芯抗弯强度溶解性熔模铸造

water-soluble waxceramic coreflexural strengthsolubilityinvestment casting

《铸造》 2026 (10)

1105-1112,8

国家部委基础科研计划项目(JCKY2024213B002)国家自然科学基金(52402094).

10.27014/j.cnki.zhuzao.2026.0141

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