首页|期刊导航|火炸药学报|降速剂对NEPE推进剂燃烧性能的影响

降速剂对NEPE推进剂燃烧性能的影响OA

Effect of Burning Rate Inhibitor on Combustion Performance of NEPE Propellant

中文摘要英文摘要

采用SEM-EDS和激光粒度分析仪表征了降速剂多芳烃氮磷杂环化合物(BRI)的形貌和粒度;采用DSC法研究了 BRI对AP、HMX和聚醚黏合剂热分解行为的影响;分析了 BRI对NEPE推进剂爆热、燃烧性能和燃烧火焰影响.结果表明,BRI降速剂材料主要由O元素、P元素和C元素组成;BRI对AP、HMX和聚醚黏合剂热分解温度影响不大,能够降低推进剂爆热、燃速和压强指数,爆热由6 362.0J/g降至5 948.0J/g,7MPa燃速由7.17mm/s降至6.81mm/s,3~15MPa压强指数由0.82降至0.78.添加BRI后,燃面处的珊瑚状熔联体数量明显增加,铝粉的熔联团聚现象加剧.

The morphology and particle size of burning rate inhibitor(BRI)was characterized by SEM-EDS and laser particle size analyzer.The effect of BRI on the thermal decomposition behavior of AP,HMX and polyether adhesives were studied by DSC.The influence of BRI on the heat of explosion,combustion performance and combustion flame of NEPE propellant were analyzed.The results show that BRI was mainly composed of O element,P element and C element;BRI has little effect on the thermal decomposition temperature of AP,HMX and polyether binder,and it can reduce the heat of explosion,burning rate and pressure exponent of the propellant,the heat of explosion decreased from 6362.0J/g to 5948.0J/g,the burning rate at 7 MPa decreased from 7.17 mm/s to 6.81 mm/s,and the pressure exponent over the pressure range of 3-15 MPa decreased from 0.82 to 0.78.With the addition of BRI,the number of coral-like fusible units on the burning surface increased obviously,and the agglomeration of aluminum powder was intensified.

李伟;刘洋洋;郭翔;汪越;朱浩

北京航空航天大学,北京 100191||湖北航天化学技术研究所,湖北襄阳 441003襄阳职业技术大学,湖北襄阳 441003湖北航天化学技术研究所,湖北襄阳 441003湖北航天化学技术研究所,湖北襄阳 441003北京航空航天大学,北京 100191

军事科技

物理化学聚醚推进剂燃速调节剂爆热燃烧性能燃烧火焰

physical chemistrypolyether propellantburning rate inhibitorheat of explosioncombustion performancecom-bustion flame

《火炸药学报》 2026 (9)

1001-1007,7

10.14077/j.issn.1007-7812.202601023

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