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基于逐步回归的生物航煤属性鉴别OA

Attribute Identification of Bio-aviation Jet Fuel via Stepwise Regression

中文摘要英文摘要

针对现行航空喷气燃料标准仅规定常规指标,无法鉴别来源(石油基、生物基或混合),存在监管盲区的实际情况,该文提出逐级鉴别策略(主要成分初筛-理化性质定性-生物基碳含量确证),有效鉴别出酯和脂肪酸加氢改质工艺生产的生物航煤(HEFA-SPK)的属性鉴别.首先,基于气相色谱-质谱(GC-MS)分析,排除碳数分布不在C6~C17的燃料;其次依据密度及芳烃含量快速定性,辅以馏程、闪点综合评判;最后以生物基碳含量确证,高于97.0%时判定为纯生物基燃料,低于0.5%时认定为石油基燃料.掺混比例在1%~30%范围时,采用逐步回归构建基于闪点、馏程宽度及生物基碳含量的掺混比例预测模型,并经配对t检验验证.结果表明,模型可准确预测HEFA-SPK掺混比例(R²>0.99),为生物航煤监管与来源识别提供技术支撑.

Current aviation jet fuel specifications only prescribe basic technical indicators,thus cre-ating a regulatory gap because they cannot effectively distinguish between conventional petroleum-de-rived sources,bio-based sources,or their blends.To address this issue,a stepwise identification strategy comprising component screening,rapid physicochemical qualitative analysis,and bio-based carbon content confirmation is proposed for the attribute identification of hydroprocessed esters and fatty acids synthetic paraffinic kerosene(HEFA-SPK).First,gas chromatography-mass spec-trometry is performed to screen the carbon number distribution;samples outside the typical aviation fuel range(C6-C17)are excluded.Subsequently,rapid qualitative discrimination is achieved based on density and aromatic content,supplemented by distillation range and flash point as auxiliary pa-rameters for a comprehensive evaluation.Finally,bio-based carbon content serves as the key evi-dence:a measured content above 97.0%identifies HEFA-SPK,while a value below 0.5%indicates petroleum-based jet fuel.For intermediate blending ratios(1%-30%),a stepwise regression ap-proach is employed to develop a predictive model for the blending ratio of bio-based fuel,and the model is validated via a paired t-test.Results show that the linear regression model based on flash point,distillation range,and biogenic carbon content accurately predicts the blending ratio(R²>0.99),thus providing reliable technical support for the quality supervision and source identification of bio-based aviation fuel.

夏莹;段逸品;张子豪;蔡国田;肖前

广州海关技术中心,广东 广州 510623||中国科学院广州能源研究所,广东 广州 510640广州海关技术中心,广东 广州 510623广州海关技术中心,广东 广州 510623中国科学院广州能源研究所,广东 广州 510640广州海关技术中心,广东 广州 510623

化学化工

酯和脂肪酸加氢改质工艺生产的生物航煤(HEFA-SPK)属性鉴别生物基碳含量掺混比例

hydroprocessed esters and fatty acids synthetic paraffinic kerosene(HEFA-SPK)at-tribute identificationbiogenic carbon contentblending ratio

《分析测试学报》 2026 (10)

2171-2178,8

广州海关科研项目(2025GZCK08)海关总署科研项目(2025HK243)

10.12452/j.fxcsxb.26071601

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