手性BODIPY圆偏振发光材料:分子设计及其应用OA
Chiral BODIPY Circularly Polarized Luminescence Materials:Molecular Design and Applications
圆偏振发光(CPL)材料能够携带光的旋光性信息,在光电信息、生物医药及防伪材料等领域具有广阔的应用前景,其发光不对称因子(glum)与量子产率的协同优化是实现高性能圆偏振发光的关键.在众多CPL分子中,手性硼二吡咯亚甲基(BODIPY)分子因其结构多样性、可调控的发光特性及高发光效率而备受关注.本文综述了具有CPL活性的手性BODIPY发光材料在设计、合成及光物理性质方面的最新进展,及其在生物成像与光电材料领域的研究,以期为手性发光材料的功能化设计与应用提供参考.
Circularly polarized luminescence(CPL)materials encode chiral optical information,showing promise for optoelectronics,biomedicine,and anti-counterfeiting.Achieving high-performance CPL requires concurrent opti-mization of the dissymmetry factor(glum)and quantum yield.Chiral boron dipyrromethene(BODIPY)derivatives have emerged as attractive candidates due to their structural versatility,tunable emission,and high brightness.This review summarizes recent advances in the design,synthesis,and photophysical properties of CPL-active chiral BODIPYs,alongside their applications in bioimaging and optoelectronic materials.This work aims to guide the func-tional design of chiral luminescent systems.
孟岩恒;原焱焱;薛雨婷;陈磅宽
北京理工大学化学与化工学院,北京 102488北京理工大学化学与化工学院,北京 102488北京理工大学化学与化工学院,北京 102488北京理工大学化学与化工学院,北京 102488
数理科学
圆偏振发光手性BODIPY生物成像光电材料
circularly polarized luminescencechiral BODIPYbioimagingoptoelectronic materials
《发光学报》 2026 (9)
1638-1653,16
国家自然科学基金(22271013,22471014)中央高校基本科研业务费专项资金(2025CX11028)Supported by National Natural Science Foundation of China(22271013,22471014)Fundamental Research Funds for the Cen-tral Universities(2025CX11028)
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