四苯乙烯手性组装体系的圆偏振发光与调控研究进展OA
Research Progress on Circularly Polarized Luminescence and Regulation of Tetraphenylethene Chiral Assembly System
圆偏振发光材料因其在下一代显示技术、信息加密、手性传感与识别等领域的应用前景而受到广泛关注.然而,传统发光材料在固态或聚集状态下常因聚集诱导猝灭效应而导致发光效率下降,限制了其实际应用,聚集诱导发光现象的发现为解决这一问题提供了新思路.四苯乙烯基元因其结构易于修饰、固态发光效率高、聚集行为可控等优点,成为构建高性能圆偏振发光材料的理想平台.本文总结了四苯乙烯圆偏振发光材料在手性组装策略、聚集态手性放大机制、性能调控手段及应用探索等方面的最新研究进展.
Circularly polarized luminescent materials have garnered significant attention due to their broad applica-tion prospects in next-generation display technologies,information encryption,chiral sensing,and recognition.How-ever,conventional luminescent materials often suffer from reduced emission efficiency in the solid or aggregated state due to aggregation-caused quenching,which limits their practical applications.The discovery of aggregation-induced emission offers a new strategy to overcome this challenge.The tetraphenylethene motif,with its ease of structural modification,high solid-state emission efficiency,and controllable aggregation behavior,serves as an ideal platform for constructing high-performance circularly polarized luminescent materials.This article systematically reviews re-cent research progress on tetraphenylethene-based circularly polarized luminescent materials,focusing on chiral as-sembly strategies,mechanisms of chirality amplification in the aggregated state,performance regulation methods,and explorations of practical applications.
贾文萱;贾鸿哲;徐立进;欧阳光辉
中国人民大学化学与生命资源学院,北京 100872中国人民大学化学与生命资源学院,北京 100872中国人民大学化学与生命资源学院,北京 100872中国人民大学化学与生命资源学院,北京 100872
数理科学
四苯乙烯圆偏振发光聚集诱导发光超分子手性超分子组装
tetraphenylethylenecircularly polarized luminescenceaggregation-induced luminescencesupramo-lecular chiralitysupramolecular assembly
《发光学报》 2026 (9)
1607-1619,13
国家自然科学基金(22322207,92356307)Supported by National Natural Science Foundation of China(22322207,92356307)
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