Tb3+→Sm3+能量传递调控的多色应力发光材料及其动态防伪应用OA
Tunable-color Mechanoluminescent Materials via Tb3+→Sm3+Energy Transfer for Dynamic Anti-counterfeiting Application
应力发光(ML)材料凭借独特的机械-光能转换能力,在多领域具有广泛应用前景,而多色特性可进一步拓展其应用边界.能量传递是调控发光材料性能的核心机制,但应力发光材料中可实现能量传递以调节色度的材料极少.本文通过高温固相法制备了 Na2CaP2O7:Tb3+,Sm3+系列荧光粉,构建了 Tb3+→Sm3+的能量传递通道,实现了应力发光颜色的调节.在此基础上,利用应力发光的颜色与强度差异记录机械作用轨迹及力度,设计了动态信息加密与防伪应用.该研究不仅为设计新型多色应力发光材料提供了有效策略,也拓展了应力发光材料在先进信息安全领域的应用场景.
Mechanoluminescent(ML)materials,by virtue of their unique capability for mechanical-to-optical en-ergy conversion,hold great promise for a wide range of applications,and the development of multicolor properties can further broaden their application scope.Energy transfer is a core mechanism for tuning the properties of lumines-cent materials.However,ML materials that utilize energy transfer to adjust chromaticity are extremely rare.In this study,a series of Na2CaP2O7:Tb3+,Sm3+phosphors are prepared via a high-temperature solid-state method.An ener-gy transfer channel from Tb3+to Sm3+is successfully established,enabling the tuning of ML colors.Based on this,we design an application for dynamic information encryption and anti-counterfeiting by utilizing the variations in ML col-or and intensity to record the trajectory and magnitude of the applied mechanical force.This research not only pro-vides an effective strategy for designing novel multicolor ML materials but also broadens their application scenarios in the field of advanced information security.
孟京;岳梦迪;贾振威;贾云尧;武莉;孔勇发;许京军
南开大学物理科学学院,天津 300071南开大学物理科学学院,天津 300071南开大学物理科学学院,天津 300071南开大学物理科学学院,天津 300071南开大学物理科学学院,天津 300071南开大学物理科学学院,天津 300071南开大学物理科学学院,天津 300071
数理科学
Na2CaP2O7:Tb3+,Sm3+能量传递应力发光动态防伪
Na2CaP2O7:Tb3+,Sm3+energy transfermechanoluminescencedynamic anti-counterfeiting
《发光学报》 2026 (9)
1586-1597,12
国家自然科学基金(12274244,12574441)Supported by National Natural Science Foundation of China(12274244,12574441)
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