配煤对煤灰熔融温度和黏温特性的影响OA
The Impact of Coal Blending on the Melting Temperature and Viscosity Characteristics of Coal Ash
针对榆林地区煤灰的熔融温度(tm)、黏度(η)与气化工艺要求不匹配问题,采用榆林地区6种煤(金鸡滩沫煤、5种精煤)进行配煤实验,研究配煤对tm、η的影响.结果表明,随着混入精煤质量(m)增加,配煤煤灰的tm、η呈非线性降低趋势;FactSage模拟结果显示,随着配煤煤灰中碱性组分质量分数(wa)增加,熔渣中生成的低熔点矿物质(如CaAl2Si2O8)增多,导致煤灰tm降低;配煤J8H2煤灰虽呈玻璃渣状态,但其η较高,易导致气化炉结渣;随着混入精煤的m增加,煤灰呈现结晶渣状态,但η=2.5~25.0 Pa·s下对应的温度范围扩大,利于气化炉稳定运行;非桥氧键、桥氧键的计算结果(nNBO/nBO)显示,混入精煤的m增加,降低了煤灰熔渣的硅酸盐网络结构稳定性,导致煤灰的η下降.配煤有效调控了榆林煤灰的tm、η,为煤在气化炉中的高效利用提供了理论依据.
To address the mismatch between the melting temperature(tm)and viscosity(η)of coal ash in the Yulin area and the requirements of gasification process,coal blending was conducted using six types of local coal(Jinjitan slack coal and five cleaned coals)to study the effect of coal blending on tm and η.The results indi-cate that with an increase in the mass of cleaned coal(m)blended,the tm and η of coal ash slag exhibit a nonlin-ear decreasing trend.FactSage simulation results show that as the mass fraction of alkaline components(wa)in the coal ash slag increases,the amount of low-melting-point minerals(such as CaAl2Si2O8)increases,leading to a decrease in the tm of coal ash slag.Although J8H2 coal ash exhibits a glassy slag state,its η is relatively high,which can easily lead to slagging in the gasifier.With an increase in the mass of blended cleaned coal(m),the coal ash slag shows a crystalline slag state,but the temperature range corresponding to η=2.5-25.0 Pa·s is expanded,which is beneficial for the stable operation of the gasifier.The calculation results of non-bridging oxygen bonds and bridging oxygen bonds(nNBO/nBO)show that an increase in the mass of blended cleaned coal(m)reduces the stability of the silicate network structure of coal ash slag,resulting in a decrease in η.Coal blending effectively regulates the tm and η of Yulin coal,providing a theoretical basis for its efficient utili-zation in gasifiers.
冯斌;赵薇;李伟;宋旭东;白永辉;于广锁
宁夏大学 省部共建煤炭高效利用与绿色化工国家重点实验室,宁夏 银川 750021||兖州煤业榆林能化有限公司,陕西 榆林 718000宁夏大学 省部共建煤炭高效利用与绿色化工国家重点实验室,宁夏 银川 750021兖州煤业榆林能化有限公司,陕西 榆林 718000宁夏大学 省部共建煤炭高效利用与绿色化工国家重点实验室,宁夏 银川 750021宁夏大学 省部共建煤炭高效利用与绿色化工国家重点实验室,宁夏 银川 750021宁夏大学 省部共建煤炭高效利用与绿色化工国家重点实验室,宁夏 银川 750021||兖州煤业榆林能化有限公司,陕西 榆林 718000||华东理工大学 洁净煤技术研究所,上海 200030
化学化工
配煤煤灰熔融温度黏温特性非桥氧键与桥氧键
coal blendingmelting temperature of coal ashviscosity temperature characteristicsnon-bridging oxygen bonds and bridging oxygen bonds
《宁夏大学学报(自然科学版中英文)》 2026 (5)
451-457,7
国家自然科学基金资助项目(22108132)
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