含能低共熔物熔铸载体炸药的研究进展OA
Research Progress on Energetic Eutectic Mixtures as Melt-Cast Carrier Explosives
熔铸载体炸药是熔铸炸药体系中不可或缺的低熔点组分,其性能直接决定熔铸炸药的工程应用效果.针对传统熔铸载体炸药2,4,6-三硝基甲苯(TNT)应用的局限,含能低共熔物凭借热化学性质、安全性和能量性能可调控的优势,成为了当前含能材料领域的研究热点.本文系统阐述了含能低共熔物T-X相图、H-X相图的构建方法,梳理了利用相图获取最低共熔物组成配比、低共熔温度及相态分布特征的技术路径,分类总结了1,3,3-三硝基氮杂环丁烷(TNAZ)、3,4-二硝基呋咱基氧化呋咱(DNTF)、1-甲基-3,4,5-三硝基吡唑(MTNP)等系列典型含能低共熔物的最新研究成果.结合目前领域内的研究现状,对含能低共熔物后续研发重点与应用前景进行展望,可为新型低感高能熔铸载体炸药的设计与配方优化提供参考.
Melt-cast carrier explosives are fundamental low-melting-point constituents for melt-cast explosive formulations,and their properties are critical to the engineering practicability of melt-cast explosives.To address the inherent drawbacks of the tra-ditional melt-cast carrier explosive 2,4,6-trinitrotoluene(TNT),energetic eutectic mixtures have emerged as a popular research focus,benefiting from their tunable thermochemical properties,energy and safety performances.Methods for constructing T-X and H-X phase diagrams of energetic eutectic mixtures are elaborated,alongside approaches to determine their compositions,melting points and phase distribution rules.Additionally,the state-of-the-art studies on energetic eutectic mixtures based on 1,3,3-trinitroazetidine(TNAZ),3,4-dinitrofurzanfuroxan(DNTF),1-methyl-3,4,5-trinitropyrazole(MTNP)are discussed.On the basis of current research situation,the development potential and core research directions of energetic eutectic mixtures are pro-posed.This work intends to facilitate the design and formula optimization of novel low-sensitivity,high-energy melt-cast explo-sives.
王滨燊;金波;彭汝芳
西南科技大学材料与化学学院环境友好能源材料国家重点实验室,四川 绵阳 621010西南科技大学材料与化学学院环境友好能源材料国家重点实验室,四川 绵阳 621010西南科技大学材料与化学学院环境友好能源材料国家重点实验室,四川 绵阳 621010
军事科技
含能分子低共熔物熔铸载体炸药相图熔点
energetic moleculeseutectic mixturemelt-cast carrier explosivesphase diagrammelting point
《含能材料》 2026 (9)
1068-1079,12
国家自然科学基金(22575203),四川省科技计划青年科技创新研究团队项目(2026NSFSCZY0069),四川省自然科学基金重 点 项 目(2025ZNSFSC0036),西 南 科 技 大 学 科 研 基 金 资 助(25zx7112)National Natural Science Foundation of China(No.22575203),Sichuan Science and Technology Program(No.2026NSFSCZY0069),Key Program of the Natural Science Foundation of Sichuan Province(No.2025ZNSFSC0036),Re-search Foundation of Southwest University of Science and Technology(No.25zx7112)
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