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HPAL-MHP-萃取一体化流程中前端开路分流杂质的工艺与经济性分析OA

Process and Economic Evaluation of Upstream Open-Loop Impurity Separation in an Integrated HPAL-MHP-Solvent Extraction Flowsheet

中文摘要英文摘要

本文基于红土镍矿经湿法冶金制备碳酸锰产品的工艺流程,分析了锰在各阶段的存在形态及其转化规律.结果表明,锰在高压酸浸阶段以Mn²⁺形态进入溶液,在后续除铁铝及沉镍钴过程中大部分仍以溶解态迁移,难以有效分离.结合热力学分析与电位~pH关系,提出在第二段沉镍工序中提高pH至8.0~9.0并鼓入空气,可促使Mn²⁺氧化为MnO₂沉淀,从体系中开路排出.该改进方案可降低萃取段负荷,减少杂质干扰,为红土镍矿湿法生产碳酸锰及后续镍钴精制提供可行的工艺优化思路.

This paper is based on the technological process of preparing manganese carbonate products from laterite nickel ore through hydrometallurgy.It analyzes the existence forms of manganese in each stage and its transformation laws.The research shows that manganese enters the solution in the form of Mn²⁺ during the high-pressure acid leaching stage.During the subsequent iron-aluminum removal and nickel-cobalt precipitation processes,most of it still migrates in a dissolved state,making effective separation difficult.Combining thermodynamic analysis with the potential-pH relationship,it is proposed that in the second-stage nickel precipitation process,by increasing the pH to 8.0-9.0 and introducing air,Mn²⁺can be oxidized into MnO₂ precipitate and discharged from the system in an open-circuit manner.This improved scheme can reduce the load in the extraction stage,reduce impurity interference,and provide a feasible process optimization idea for the wet production of manganese carbonate from laterite nickel ore and subsequent nickel-cobalt refining.

吕昂;闫晓丹;吴康平;王强

瑞木镍钴管理(中冶)有限公司,北京 100084瑞木镍钴管理(中冶)有限公司,北京 100084瑞木镍钴管理(中冶)有限公司,北京 100084瑞木镍钴管理(中冶)有限公司,北京 100084

矿业与冶金

红土镍矿锰氧化开路

laterite-nickel oremanganese oxidation open circui

《世界有色金属》 2026 (15)

16-18,3

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