甘油氢解制备C3含氧化学品的研究进展OA
Research advances in the hydrogenolysis of glycerol to C3 oxygenated chemicals
生物柴油产业的快速发展对实现"双碳"目标、推进能源结构转型具有重要的科学意义,但副产物甘油过剩限制了生物柴油产业的进一步发展.因此,将副产物甘油进行绿色转化有利于生物柴油产业的良性发展.由甘油氢解制备C3含氧化学品是甘油绿色转化研究中最具应用前景的途径之一.本工作介绍了甘油化学及氢解反应机理,重点综述了近年来甘油氢解制备1,2-丙二醇、1,3-丙二醇、正丙醇和丙醛等高值C3含氧化学品催化剂的研究进展,并展望了甘油氢解反应未来发展的方向与趋势.
The rapid expansion of the biodiesel industry plays a crucial role in achieving carbon neutrality and promoting energy system transformation.However,the oversupply of the by-product glycerol has hindered the sustainable development of biodiesel industry.Therefore,the green conversion of the by-product glycerol is conducive to the sustainable development of the biodiesel industry.Among various valorization routes,the hydrogenolysis of glycerol to C3 oxygenated chemicals is considered one of the most promising pathways.This review first briefly introduces glycerol chemistry and the fundamental reaction mechanism of glycerol hydrogenolysis.Subsequently,recent advances in catalytic systems for the selective hydrogenolysis of glycerol to high-value C3 oxygenated chemicals such as 1,2-propanediol,1,3-propanediol,1-propanol and propanal,are comprehensively summarized.Finally,future research directions and development trends in glycerol hydrogenolysis are discussed.
毛红宇;王飞;贡红辉
河南理工大学化学化工学院 河南省煤炭绿色转化重点实验室,河南焦作 454003河南理工大学化学化工学院 河南省煤炭绿色转化重点实验室,河南焦作 454003河南理工大学化学化工学院 河南省煤炭绿色转化重点实验室,河南焦作 454003
化学化工
甘油氢解C3含氧化学品生物质
glycerolhydrogenolysisC3 oxygenated chemicalsbiomass
《燃料化学学报（中英文）》 2026 (9)
1-19,19
Supported by National Natural Science Foundation of China(22308089),Henan Provincial Science and Technology Research Project(242102241023).
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