临氢环境橡胶密封材料氢浓度特性研究进展OA
Review on Hydrogen Concentration Characteristics of Rubber Sealing Materials in Hydrogen Atmosphere
橡胶材料广泛应用于高压氢密封部件,在氢能储运领域中起着至关重要的作用.然而,高压氢环境会促使氢向橡胶材料内部溶解,加剧材料性能的劣化,最终导致材料发生密封失效.氢浓度是评价橡胶密封材料氢溶解能力的关键指标之一,研究高压氢环境下橡胶密封材料的氢浓度特性可为防治橡胶材料氢致密封失效提供理论依据.聚焦高压氢环境用橡胶密封材料,首先探讨氢在橡胶密封材料中的存在状态;随后介绍3种常见橡胶密封材料氢浓度测试方法的试验流程、理论计算过程以及试验现状,总结3种测试方法的优势与不足;最后讨论试样尺寸、氢气压力、填料种类以及橡胶种类4种因素对橡胶密封材料氢浓度的影响.基于上述分析,针对现有橡胶密封材料氢浓度特性的研究提出了若干建议,包括扩充橡胶密封材料氢浓度影响因素的研究、构建典型橡胶密封材料氢浓度数据库以及搭建高压氢环境下橡胶密封材料氢浓度的原位测试系统.
Rubber materials are widely used in high-pressure hydrogen sealing components,which play a crucial role in the field of hydrogen energy storage and transportation.However,the high-pressure hydrogen atmosphere can contribute to the dissolution of hydrogen into the interior of rubber materials,exacerbating the deterioration of the material properties and ultimately leading to seal failure.Hydrogen concentration is one of the key indicators for evaluating the hydrogen solubility of rubber sealing materials,and the study of the hydrogen concentration characteristics of rubber sealing materials under high-pressure hydrogen atmosphere can provide a theoretical basis for preventing and controlling the hydrogen-induced seal failure of rubber.Rubber sealing materials for high-pressure hydrogen atmosphere are focused on,firstly,the existence state of hydrogen in rubber sealing materials is discussed,then the test procedure,theoretical calculation process and the current status of three common hydrogen concentration tests of rubber sealing material are introduced,the advantages and shortcomings of these three tests are summarized,and finally the effect of specimen size,hydrogen pressure,filler type and rubber type on the hydrogen concentration of rubber sealing materials are discussed.Based on the above analysis,several suggestions are put forward for the research on the hydrogen concentration characteristics of rubber sealing materials,including expanding the research on the influencing factors of hydrogen concentration of rubber sealing materials,constructing a database of hydrogen concentration of typical rubber sealing materials,and building an in-situ testing system for hydrogen concentration of rubber sealing materials under high-pressure hydrogen atmosphere.
周池楼;刘一程;戴鹏智
华南理工大学 机械与汽车工程学院,广州 510641||华南理工大学 教育部传热传质与低碳转化重点实验室,广州 510641华南理工大学 机械与汽车工程学院,广州 510641华南理工大学 机械与汽车工程学院,广州 510641
化学化工
氢密封聚合物氢浓度安全溶解橡胶
hydrogensealpolymerhydrogen concentrationsafetydissolutionrubber
《机电工程技术》 2026 (16)
1-9,62,10
国家自然科学基金(52575178)广东省重点研发计划(2024B1111080002)广东省基础与应用基础研究基金(2026A1515011013)
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