反应热压烧结制备(Zr0.5Ta0.5)B2-SiC复相陶瓷的组织结构演化及抗氧化性能OA

Ultra-high temperature ceramics(UHTCs)are regarded as highly promising materials for aerospace applications due to their exceptional thermal and mechanical stability under harsh environmental conditions.In this study,to further enhance the performance of UHTCs across a broad temperature range,multiphase ceramics are fabricated through a combination of in-situ reaction and hot-pressing techniques,utilizing TaSi2,ZrSi2,B4C,and C as raw materials.Subsequently,the microstructure,micromechanical properties,and oxidation resistance of the prepared ceramics are thoroughly investigated.The results reveal that the ZrB2-TaB2-SiC multiphase ceramic is formed at 1200℃.As the temperature increasing to 1500℃,the ZrB2-TaB2-SiC ceramic undergoes an in-situ solid-solution reaction,transforming into(Zr0.5Ta0.5)B2-SiC.In terms of mechanical properties,the hardness values are 12.59 GPa for ZrB2-TaB2-SiC and 15.11 GPa for(Zr0.5Ta0.5)B2-SiC,respectively.Similarly,the fracture toughness values are 3.66 MPa·m1/2 for ZrB2-TaB2-SiC and 5.89 MPa·m1/2 for(Zr0.5Ta0.5)B2-SiC,respectively.Thermogravimetric analysis demonstrates that the(Zr0.5Ta0.5)B2-SiC solid-solution multiphase ceramics exhibit outstanding oxidation resistance.Specifically,the mass gain is only 0.48 mg/cm2 when the temperature reaches up to 1600℃.The mechanism underlying this excellent oxidation resistance can be attributed to synergistic effect of multiphase oxides,which stabilizes oxidation film and reduces diffusion rate of oxygen.