轻质油催化裂解耦合流化床反应器过渡段数值模拟OA
Simulation of transition section in a light oil catalytic cracking coupled fluidized bed reactor
轻质油催化裂解是石油化工中的重要工艺,新型提升管-湍流床-密相床催化裂解耦合反应器可优化催化裂解过程中的传质、传热性能并提升反应效率.相较于传统反应器,耦合反应器具备更高的反应速率、更优异的温度控制能力与更长的催化剂使用寿命,进而提升产物选择性与收率.其中,耦合流化床过渡段作为连接提升管和流化床的重要结构,在优化气固流动和提升反应效率方面具有显著优势.本文重点分析了耦合流化床过渡段的气固两相流动特性,以及气固两相在大孔分布板上的流动规律,进一步改变大孔分布板的布孔方式,研究其对变径段流动特性和返混现象的影响.基于欧拉-欧拉双流体模型及能量最小化多尺度曳力模型,针对该反应器过渡段开展数值模拟研究.通过网格无关性验证,并结合镜面反射系数的合理选取与黏度模型的优化,构建出与实验数据吻合度良好的数值模型.结果表明,随着变径段内气速增加,边壁区域的固含率随之增加,颗粒从中心区域向边壁区域运动的程度更加剧烈,中心区域的气速高于带出速度是形成返混现象的主要原因;增大大孔分布板近圆心处的孔间距,可提高变径段边壁返混速度并改善边壁颗粒聚集现象,同时减小气体返混范围,进一步平衡内外层流体分布,能有效减少大孔分布板与变径段边壁夹角处的颗粒滞留,显著提升气固两相分布的均匀性.
Light oil catalytic cracking is an important process in petrochemical industry.The new type of riser-turbulent bed-dense phase bed catalytic cracking coupled reactor can optimize the mass transfer,heat transfer performance and reaction efficiency during the catalytic cracking process.Compared with traditional reactors,the coupled reactor has higher reaction rate,better temperature control capability and longer catalyst service life,thereby improving the product selectivity and yield.Among them,the transition section of the coupled fluidized bed,as an important structure connecting the riser and the fluidized bed,has significant advantages in optimizing gas-solid flow and improving reaction efficiency.The focus of this study was to analyze the gas-solid two-phase flow characteristics in the transition section of a coupled fluidized bed.Furthermore,the orifice arrangement of the large-orifice distributor was modified to investigate its effects on the flow characteristics.Based on the Euler-Euler two-fluid model and the energy-minimization multi-scale(EMMS)drag model,numerical simulation studies were carried out for the transition section of the reactor.Through grid independence verification,combined with the reasonable selection of the specular reflection coefficient and the optimization of the viscosity model,a numerical model with good agreement with the experimental data was established.The simulation results showed that with the increase of gas velocity in the variable-diameter section,the solid holdup in the wall region increased accordingly,and the movement of particles from the central region to the wall became more intense;the main reason for the formation of backmixing was that the gas velocity in the central region was higher than the entrainment velocity.Increasing the orifice spacing near the center of the large-orifice distributor could improve the backmixing velocity of the variable-diameter section wall and the particle accumulation on the wall,while reducing the gas backmixing range.Further balancing the fluid distribution between the inner and outer layers could effectively reduce particle retention at the angle between the large-orifice distributor and the variable-diameter section wall,and significantly improve the uniformity of gas-solid two-phase distribution.
孙富伟;刘梦溪;卢春喜
中国石油大学(北京)化学工程与环境学院,北京 102249||中国昆仑工程有限公司,北京 100037中国石油大学(北京)化学工程与环境学院,北京 102249中国石油大学(北京)化学工程与环境学院,北京 102249
化学化工
耦合流化床过渡段大孔分布板流动特性轻质油催化裂解
coupled fluidized bedtransition sectionlarge-orifice distributorflow characteristicscatalytic cracking of light oil
《化工进展》 2026 (8)
4538-4561,24
评论