基于24种脂质标志物降解动力学的指纹遗留时间预测模型研究OA
Research on Fingerprint Time Since Deposition Prediction Model Based on Degradation Kinetics of 24 Kinds of Lipid Biomarkers
预测指纹遗留时间能够为案发时间的推断和证言可靠性的评估提供依据,起到缩小侦查范围的效果.本研究基于气相色谱-质谱法(GC-MS)定量分析了遗留指纹中23种脂肪酸和角鲨烯的含量范围.将24种脂质两两组合构建276组脂质比值对全量特征集,通过斯皮尔曼单变量分析筛选出与指纹遗留时间显著相关的比值特征,结合随机森林算法的Gini重要性评分探究了特征对预测模型的非线性贡献度,最终构建基于脂质比值特征的指纹遗留时间预测模型.结果表明,此模型能够有效区分遗留时间为0、9、13 d的指纹,且具有良好的跨个体鲁棒性.整体模型性能决定系数(R2)为0.785,均方根误差(RMSE)为2.10 d.本研究为指纹遗留时间的精准预测提供了新的技术思路与量化依据.
Predicting the age of fingerprint impressions can provide a basis for inferring the time of crime occurrence and evaluating the reliability of testimonies,effectively narrowing down the scope of investigation.In this study,the content ranges of 23 kinds of fatty acids and squalene in fingerprint impressions were quantitatively analyzed using gas chromatography-mass spectrometry(GC-MS).By combining 24 types of lipids in pairs,276 lipid ratio feature sets were constructed.Spearman's univariate analysis was used to screen ratio features significantly correlating with the age of fingerprint impressions.The Gini importance scores of the random forest algorithm were combined to explore the nonlinear contribution of features to the prediction model,ultimately constructing a fingerprint age prediction model based on lipid ratio features.The results showed that the model could effectively distinguish fingerprint impressions left for 0,9,and 13 d,and exhibited good cross-individual robustness.The overall model performance had a coefficient of determination(R2)of 0.785 and a root mean squared error(RMSE)of 2.10 d.This study provided new technical insights and quantitative evidence for accurate prediction of fingerprint age.
张文骥;易梓琛
中国刑事警察学院刑事科学技术学院,沈阳 110854中国刑事警察学院刑事科学技术学院,沈阳 110854
指纹指纹遗留时间脂质随机森林气相色谱-质谱法
FingerprintTime since deposition of fingerprintLipidRandom forestGas chromatography-mass spectrometry
《分析化学》 2026 (8)
1411-1422,12
沈阳市中青年科技人才培养专项项目(No.RC240610)、辽宁省教育厅基本科研项目(No.JYTMS20261415)和中央高校基本科研业务费项目(No.980237)资助. Supported by the Shenyang Special Project for Cultivating Young and Middle-aged Scientific and Technological Talents(No.RC240610),the Basic Scientific Research Project of Liaoning Provincial Department of Education(No.JYTMS20261415)and the General Project of Basic Scientific Research Funds for Central Universities(No.980237).
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