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氧化锆增韧氧化铝陶瓷增韧增强技术研究进展OA

Research progress in toughening and strengthening technologies of zirconia toughened alumina ceramics

中文摘要英文摘要

同步提升氧化锆增韧氧化铝(Zirconia Toughened Alumina,ZTA)陶瓷的韧性、强度与硬度,是拓展其相关应用的基础.通过文献调研与对比,分析了第三相添加剂与烧结致密化技术对微观结构的改性机理.结果表明,引入稳定剂可优化相变增韧效应,原位生成片状次生相能诱发裂纹偏转与桥联,二者通过激活多元增韧机制显著提升断裂韧性.在烧结工艺方面,分析了放电等离子烧结、振荡压力烧结、两步烧结法等先进技术对致密化动力学的调控作用,其核心在于通过抑制晶粒粗化与消除闭口气孔,实现硬度与韧性的协同优化.进一步基于致密化动力学模型,揭示了氧化锆对晶粒生长指数与烧结活化能的影响规律.通过总结组分优化与工艺调控的协同机制,为ZTA陶瓷高致密、细晶组织的构筑与性能增强提供参考.

The coordinated improvement of toughness,strength,and hardness is important for expanding the applications of zirconia toughened alumina(ZTA)ceramics.Through literature research and comparison,this review analyzes the modification mechanisms of third-phase additives and sintering densification technologies for microstructure control.The results indicate that stabilizers can optimize phase transformation toughening.In-situ-formed platelet-like secondary phases can induce crack deflection and bridging.These mechanisms work together to improve fracture toughness.In terms of sintering processes,advanced technologies such as spark plasma sintering,oscillatory pressure sintering,and two-step sintering regulate densification kinetics by suppressing grain coarsening and eliminating closed pores.This regulation helps optimize hardness and toughness.Furthermore,densification kinetic models clarify the effects of zirconia on the grain growth exponent and sintering activation energy.By summarizing the synergistic mechanism of compositional optimization and process regulation,this review provides a reference for preparing dense,fine-grained ZTA ceramics with enhanced mechanical properties.

廖成荣;罗建强;王焱;张濠雯;陈昊;冯哲圣

电子科技大学 材料与能源学院,四川 成都 611731中国电子科技集团第二十九研究所,四川 成都 610036电子科技大学 材料与能源学院,四川 成都 611731电子科技大学 材料与能源学院,四川 成都 611731电子科技大学 材料与能源学院,四川 成都 611731电子科技大学 材料与能源学院,四川 成都 611731

通用工业技术

氧化锆增韧氧化铝烧结工艺综述力学性能添加剂

ZTAsintering processreviewmechanical propertiesadditives

《电子元件与材料》 2026 (8)

876-884,9

国家自然科学基金(62371103)

10.14106/j.cnki.1001-2028.2026.0044

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