首页|期刊导航|应用化学|粉末锻造工艺对制备新型电池箔材用纯铝板材的组织及性能影响

粉末锻造工艺对制备新型电池箔材用纯铝板材的组织及性能影响OA

Effect of Powder Forging on the Microstructure and Properties of Commercial-Purity Aluminum for a Novel Battery Foil Material

中文摘要英文摘要

为满足电池铝箔超薄化对铝板强度、塑性及导电性的协同需求,采用粉末锻造工艺制备了新型电池铝箔用纯铝板材,系统研究了不同球磨时间和热锻温度对材料组织和性能的影响.研究表明,通过高能球磨制粉过程可制备具有高密度位错及堆垛层错特征的超细晶铝粉.热锻温度影响动态回复/再结晶过程,热锻铝板力学与导电性能呈现典型权衡关系,热锻温度为560℃的样品具有较高的抗拉强度(375.9 MPa),此时延伸率与电导率较低(1.99%、48.7%IACS);随温度升至600℃,塑性与导电性提升(4.74%、53.2%IACS),强度相应下降(抗拉强度208.64 MPa).制备得到的高强纯铝板材其抗拉强度较工业常用的铝箔轧制母材铝板提升了90%~240%,该材料高强度源于位错强化、细晶强化与层错强化的协同作用.粉末锻造工艺可在不依赖复杂时效强化的前提下实现纯铝体系强度-塑性-导电性的可调协同,可为后续箔材轧制工序提供组织与性能优良的坯料.

To meet the synergistic requirements of strength,ductility,and electrical conductivity for ultrathin battery aluminum foil,a powder-forging route was employed in this study to fabricate a novel commercial-purity Al plate for battery foil applications,and the effects of ball-milling time and hot-forging temperature on its microstructure and properties were systematically investigated.The results show that high-energy ball milling can produce ultrafine-grained Al powders characterized by a high density of dislocations and stacking faults.It was further found that the hot-forging temperature strongly affects the dynamic recovery and recrystallization behavior,and the forged Al plates exhibit a typical trade-off between mechanical properties and electrical conductivity.The sample forged at 560℃showed a relatively high ultimate tensile strength of 375.9 MPa,but low elongation and electrical conductivity of 1.99%and 48.7%IACS,respectively.When the temperature increased to 600℃,the ductility and electrical conductivity improved to 4.74%and 53.2%IACS,respectively,whereas the strength decreased accordingly,with an ultimate tensile strength of 208.64 MPa.Compared with the industrially used Al plate as the rolling stock for aluminum foil,the as-prepared high-strength pure Al plate exhibited an increase in ultimate tensile strength of 90%~240%.The high strength of this material is mainly attributed to the synergistic effects of dislocation strengthening,grain-refinement strengthening,and stacking-fault strengthening.Therefore,the powder-forging route enables tunable optimization of strength,ductility,and electrical conductivity in a pure Al system without relying on complex age-hardening treatments,and provides a billet with excellent microstructural and mechanical properties for subsequent foil-rolling processes.

崔岩琛;王吉;柳京涛;张军辰;张君凤;乔竹辉;张淼

烟台大学化学化工学院,烟台 263005烟台先进材料绿色制造山东省实验室,烟台 264005山东鲁电线路器材有限公司,烟台 265301山东鲁电线路器材有限公司,烟台 265301山东鲁电线路器材有限公司,烟台 265301烟台先进材料绿色制造山东省实验室,烟台 264005||中国科学院兰州化学物理研究所,固体润滑国家重点实验室,兰州 730000烟台大学化学化工学院,烟台 263005

化学化工

电池铝箔纯铝板材高能球磨粉末锻造

Battery aluminum foilPurity aluminum sheetHigh-energy ball millingPowder forging

《应用化学》 2026 (8)

1238-1247,10

山东省实验室项目(No.SYS202204)和山东省重大科技创新工程项目(No.2024CXGC010316)资助 Supported by Shandong Provincial Laboratory Project(No.SYS202204)and Shandong Provincial Major Innovation and Technology Development Project(No.2024CXGC010316)

10.19894/j.issn.1000-0518.260083

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