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面向智能纺织品的动态结构色光子晶体薄膜OA

Dynamic structural color photonic crystal film for smart textiles

中文摘要英文摘要

针对常规胶体纳米微球存在难以规模化制备、所构筑光子晶体结构稳定性不足等问题,为了扩展其在柔性纺织品上的实际应用,以球形度均一、尺寸可控的PS@SiO2核壳纳米微球为结构基元,将其分散于光固化型单体体系(PHEA/PC)中,制备具有鲜艳结构色的液态光子晶体,实现了光子带隙的精确调节与色彩调控.在此基础上,采用紫外光聚合法固化液态体系,成功制备出非密堆积阵列型柔性光子晶体薄膜.该薄膜具有显著的虹彩效应与良好的柔韧性,同时在受力状态下表现出明显的力致变色行为,其结构色能够随着拉伸发生蓝移,为开发新型智能可穿戴纺织材料提供了潜在的应用前景.

Aiming at conventional colloidal nanospheres faced challenges such as difficulties in large-scale preparation and insufficient stability of the constructed photonic crystal structures.In order to expand their practical application in flexible textiles,PS@SiO2 core-shell nanosphere with uniform sphericity and controllable size were used as structural units.It was dispersed in photo-curable monomer system(PHEA/PC)to prepare liquid photonic crystals with vivid structural colors,precise adjustment of the photonic band gap and color regulation were achieved.Furthermore,the liquid system was solidified via ultraviolet polymerization to successfully obtain non-close-packed array flexible photonic crystal film.The film exhibited notable iridescence and excellent flexibility,along with distinct mechanochromic behavior under strain,in which the structural color shifted toward blue as the film was stretched.It provided potential application prospects for the development of new types of smart wearable textile materials.

高益平;谭艳;李玲;李伟华;涂志文

江西工业职业技术学院,江西 南昌,330000江西工业职业技术学院,江西 南昌,330000江西工业职业技术学院,江西 南昌,330000江西工业职业技术学院,江西 南昌,330000江西工业职业技术学院,江西 南昌,330000

轻工纺织

PS@SiO2核壳纳米微球液态光子晶体结构色力致变色柔性薄膜智能纺织品

PS@SiO2 core-shell nanosphereliquid photonic crystalstructural colormechanochromicflexible filmsmart textiles

《棉纺织技术》 2026 (9)

27-33,7

10.26967/j.issn1000-7415.202602023

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