基于LNG冷能的氢液化系统分析与优化OA
Analysis and optimization of a hydrogen liquefaction system based on LNG cold energy
目的 提高氢液化系统效率,回收蒸汽甲烷重整制氢工艺中的高温余热,减少CO2 排放,满足未来能源需求.方法 提出了一种利用液化天然气冷能进行预冷的氢液化系统,该系统结合亚临界 CO2 回热朗肯循环,用以回收蒸汽甲烷重整过程中的高温余热,并捕集 CO2.通过参数分析确定关键参数对系统的影响,重点分析换热器复合曲线与设备㶲损失,基于粒子群算法对系统进行优化,并通过对比分析验证了系统的优越性.结果 优化后系统的比能耗为 6.82 kW·h/kg,性能系数为0.195,㶲效率为 59.66%,CO2 捕集率为 60.15%;系统总㶲损失为 1 071.28 kW,主要分布在汽轮机与换热器中.结论 带有余热回收的氢液化系统比常规系统比能耗低 0.66 kW·h/kg,㶲效率提高了 3.53个百分点,能效比上升了 13.37%.研究成果可为未来的氢液化工艺提供参考.
Objective This study aims to enhance the efficiency of a hydrogen liquefaction system,recover high-temperature waste heat from the steam methane reforming(SMR)hydrogen production process,reduce CO2 emissions,and meet future energy demands.Method A hydrogen liquefaction system precooled by liquefied natural gas(LNG)cold energy and combined with a subcritical CO2 regenerative Rankine cycle was proposed to recover high-temperature waste heat from SMR and capture CO2.The influence of key parameters on the system was determined through parametric analysis.The composite curves of heat exchangers and the exergy losses of the equipment were particularly analyzed.The system was optimized based on particle swarm optimization,and its superiority was demonstrated through comparative analysis.Result The results show that the specific energy consumption of the system is 6.82 kWh/kg,the coefficient of performance is 0.195,the exergy efficiency is 59.66%,and the CO2 capture rate is 60.15%.The total exergy loss of the system is 1071.28 kW,mainly distributed in steam turbines and heat exchangers.Conclusion The hydrogen liquefaction system with waste heat recovery has a specific energy consumption that is 0.66 kWh/kg lower,while the exergy efficiency is 3.53 percentage points higher and the energy efficiency ratio is 13.37%higher than that of the conventional system.The research results can serve as a reference for future hydrogen liquefaction processes.
侯君卫;王长顺;孙小虎;何亚彬
中煤科工集团沈阳研究院有限公司||煤矿安全技术国家重点实验室辽宁石油化工大学石油天然气工程学院中国石油西南油气田公司川中油气矿中国石油西南油气田公司川中油气矿
液化天然气氢液化㶲分析蒸汽甲烷重整梯级利用
LNGhydrogen liquefactionexergy analysissteam methane reformingcascade utilization
《石油与天然气化工》 2026 (4)
26-35,10
辽宁省科学技术厅"揭榜挂帅"科技攻关专项"煤矿气动定向钻进排渣及防灭火一体化智能制氮装备及技术"(2023JH1/10400016)
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