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基于失效机理分析的耐蚀抗磨高铬铜铸铁磨球开发OA

Development of Corrosion-Resistant and Wear-Resistant High Chromium Copper Cast Iron Grinding Balls Based on Failure Mechanism Analysis

中文摘要英文摘要

针对高铬铸铁磨球在湿法磨矿工况下存在的腐蚀磨损严重、使用寿命短等技术难题,通过多尺度表征与合金设计相结合的方法,系统揭示了磨球的失效机理并开发出新型高铬铜铸铁磨球.利用金相分析、扫描电镜及能谱分析等技术,发现磨球失效主要源于基体微裂纹扩展、共晶碳化物断裂以及界面贫铬区的形成.基于失效机制分析,采用铜合金化改性与热力学计算优化相结合的策略,实现了材料成分与组织的协同调控.试验结果表明,当铜含量超过1%时,磨球的自腐蚀电位提升至-0.454 V,腐蚀电流密度显著降低,耐蚀性得到明显改善.同时,铜合金化在保持HRC62高硬度的基础上,使冲击韧性提升22%.工业化应用表明,新型磨球在实际工况下的磨耗量降低9.5%~12.8%,展现出优异的工程适用性.本研究不仅为湿式磨矿工况下磨球的材料设计提供了新思路,而且对提升耐磨材料服役性能具有重要指导意义.

To address the severe corrosion-wear and short service life of high chromium cast iron grinding balls in wet grinding operations,this study employs a combined approach of multi-scale characterization and alloy design to systematically investigate the failure mechanisms and develop a novel high chromium copper cast iron grinding ball.Metallographic analysis,scanning electron microscopy,and energy spectrum analysis revealed that the failure primarily originated from matrix microcrack propagation,eutectic carbide fracture,and interfacial chromium-depleted zone formation.Based on the failure mechanism analysis,a strategy integrating copper alloying modification and thermodynamic calculation optimization was adopted to achieve synergistic regulation of material composition and microstructure.Experimental results demonstrated that when the copper content exceeded 1%,the self-corrosion potential of the grinding ball increased to-0.454 V with significant reduction in corrosion current density,indicating markedly improved corrosion resistance.Meanwhile,the copper alloying enhanced the impact toughness by 22%while maintaining high hardness of HRC 62.Industrial applications verified that the new grinding ball reduced consumption by 9.5%-12.8%under actual working conditions,demonstrating excellent engineering applicability.This research not only provides new insights for material design of grinding balls in wet grinding environments,but also offers important guidance for improving the service performance of wear-resistant materials.

韩凯歌;刘金浪;沈茂林;胡朝辉;鲍刘虎;赵莫迪;梁驹华;韩福生

伊春鹿鸣矿业有限公司,黑龙江 伊春 152500伊春鹿鸣矿业有限公司,黑龙江 伊春 152500安徽省凤形新材料科技有限公司,安徽 宣城 242300安徽省凤形新材料科技有限公司,安徽 宣城 242300安徽省凤形新材料科技有限公司,安徽 宣城 242300中国科学院合肥物质科学研究院,安徽 合肥 230031中国科学院合肥物质科学研究院,安徽 合肥 230031中国科学院合肥物质科学研究院,安徽 合肥 230031

矿业与冶金

高铬铸铁湿法磨矿腐蚀磨损铜合金化研磨介质耐磨性耐腐蚀性显微组织合金设计

high chromium cast ironwet grindingcorrosion-wearcopper alloyinggrinding mediawear resistancecorrosion resistancemicrostructurealloy design

《铸造》 2026 (8)

862-868,7

国家自然科学基金(52001304)安徽省省级科技创新攻坚计划(202523j08050015)安徽省科技攻坚计划(202423i08050036)安徽省重点研究与开发计划(2023z04020015).

10.27014/j.cnki.zhuzao.2026.0111

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