首页|期刊导航|铸造|矿化剂对3D打印硅基陶瓷型芯微观结构及力学性能的影响

矿化剂对3D打印硅基陶瓷型芯微观结构及力学性能的影响OA

The Influence of Mineralizers on the Microstructure and Mechanical Properties of 3D Printed Silica-Based Ceramic Cores

中文摘要英文摘要

传统氧化硅基陶瓷型芯虽具有良好的化学可溶性和脱芯性能,但其本征强度较低,在高温金属液体冲击下易发生开裂或变形,难以满足复杂空心叶片对型芯力学性能的要求.本研究提出引入TiO2矿化剂结合DLP增材制造的方法,旨在通过组分优化改善硅基陶瓷的致密化行为与力学性能.采用DLP光固化成形工艺制备不同TiO2掺量的陶瓷型芯,利用SEM和XRD等手段分析其微观结构演变,研究烧结温度对陶瓷型芯抗弯强度的影响.研究结果表明,TiO2的添加可与基体形成共熔液相,促进致密化.添加10wt.%TiO2的陶瓷在1 300℃烧结后气孔率显著降低为14.28%±0.22%,抗弯强度达到峰值(65.46±1.96)MPa.TiO2含量与烧结温度对微观结构具有协同调控作用,10wt.%TiO2含量通过促进液相烧结,显著提升了材料的力学性能.本研究为高性能可溶性陶瓷型芯的组分优化提供了参考依据.

Silica-based ceramic cores exhibit excellent chemical solubility and core leaching performance,yet their inherently low mechanical strength makes them prone to cracking or deformation under the scouring of high-temperature molten metal,failing to meet the mechanical requirements of complex hollow turbine blades.This study proposes a strategy combining TiO2 mineralizer with DLP additive manufacturing to improve the densification behavior and mechanical properties of silica-based ceramics via compositional optimization.Ceramic cores with different TiO2 contents were fabricated by DLP stereolithography,and their microstructural evolution was analyzed by means of SEM,XRD and other methods,while the effect of sintering temperature on the flexural strength of ceramic cores was investigated.The results demonstrate that the addition of TiO2 can form a eutectic liquid phase with the matrix,promoting densification.The ceramic with 10wt.%TiO2 sintered at 1 300℃exhibits a significantly reduced open porosity of 14.28%±0.22%and a peak flexural strength of(65.46±1.96)MPa.The TiO2 content and the sintering temperature synergistically regulate the microstructure,and the 10wt.%TiO2 content significantly enhance the mechanical properties of the material by facilitating liquid-phase sintering.This work provides a reference basis for the compositional optimization of high-performance soluble ceramic cores.

程毅明;李鹤;石小丽;管大伟;李飞

新疆大学材料科学与工程学院,新疆先进金属材料设计及应用重点实验室,新疆 乌鲁木齐 830046新疆大学材料科学与工程学院,新疆先进金属材料设计及应用重点实验室,新疆 乌鲁木齐 830046||上海交通大学材料科学与工程学院,上海市先进高温材料及其精密成形重点实验室,上海 200240新疆大学材料科学与工程学院,新疆先进金属材料设计及应用重点实验室,新疆 乌鲁木齐 830046上海交通大学材料科学与工程学院,上海市先进高温材料及其精密成形重点实验室,上海 200240上海交通大学材料科学与工程学院,上海市先进高温材料及其精密成形重点实验室,上海 200240

化学化工

陶瓷型芯DLP光固化TiO2掺杂抗弯强度微观结构液相烧结增材制造

ceramic coreDLP stereolithographyTiO2 dopingflexural strengthmicrostructureliquid-phase sinteringadditive manufacturing

《铸造》 2026 (8)

855-861,7

先进材料—国家科技重大项目(2025ZD0609600).

10.27014/j.cnki.zhuzao.2026.0110

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