Al/Ti/Ta合金化对CoCrNi中熵合金结构与性能的影响OA
Effects of Al/Ti/Ta Alloying on the Microstructure and Properties of CoCrNi Medium-Entropy Alloys
通过向CoCrNi中熵合金中引入Al/Ti/Ta三种元素,结合真空电弧熔炼,制备了一系列(CoCrNi)99.5-2x(AlTi)xTa0.5中熵合金,用以研究Al(原子分数,at.%)(1、3、5、7)、Ti(原子分数,at.%)(1、3、5、7)、Ta(0.5at.%)三种元素共掺杂对CoCrNi中熵合金微观结构演变以及力学性能的影响.结果表明,Al/Ti/Ta的引入能够促使在塑性的CoCrNi基体中生成脆性析出相.硬质第二相的析出能够在不明显降低CoCrNi中熵合金断裂应变的前提下显著提高其室温压缩强度和硬度.其中,(AlTi)7Ta0.5合金表现出了良好的强塑性平衡,压缩屈服强度和硬度分别达到了1.0 GPa和HV470左右,但仍保持23.6%的断裂应变.微观结构表征表明,析出强化和固溶强化是屈服强度和硬度增加的主要原因.
Through introducing three kinds of Al/Ti/Ta elements into the CoCrNi medium-entropy alloy,and combining with vacuum arc melting,a series of(CoCrNi)99.5-2x(AlTi)xTa0.5 medium-entropy alloys(MEAs)have been fabricated to investigate the effects of codoping with Al(atomic fraction,at.%)(1,3,5,7),Ti(atomic fraction,at.%)(1,3,5,7),and Ta(0.5at.%)on microstructural evolution and mechanical properties of the CoCrNi medium-entropy alloys.The results indicate that the inducing of Al/Ti/Ta can prompt brittle precipitate phases to generate within the ductile CoCrNi matrix.The precipitation of secondary hard phases can significantly enhance the room-temperature compressive strength and hardness without significantly decreasing the fracture strain of the CoCrNi medium-entropy alloy.Specifically,the(AlTi)7Ta0.5 alloy exhibits an excellent strength-ductility balance,achieving a compressive yield strength of approximate 1.0 GPa and a hardness of HV470,respectively,while maintaining a high fracture strain of 23.6%.Microstructural characterizations reveal that the precipitation strengthening and solid solution strengthening are primary causes of the increment in yield strength and hardness.
龚祖荣;李栋;张锐;李傲;王晓红;苏云婷;梁骁;马腾飞
全省空气动力装备智能制造重点实验室,浙江 衢州 324000全省空气动力装备智能制造重点实验室,浙江 衢州 324000全省空气动力装备智能制造重点实验室,浙江 衢州 324000全省空气动力装备智能制造重点实验室,浙江 衢州 324000全省空气动力装备智能制造重点实验室,浙江 衢州 324000全省空气动力装备智能制造重点实验室,浙江 衢州 324000全省空气动力装备智能制造重点实验室,浙江 衢州 324000全省空气动力装备智能制造重点实验室,浙江 衢州 324000
矿业与冶金
中熵合金析出相微观组织力学性能共合金化析出强化抗压屈服强度强塑性平衡
medium-entropy alloyprecipitated phasemicrostructuremechanical propertyco-alloyingprecipitation strengtheningcompressive yield strengthstrength-ductility balance
《铸造》 2026 (8)
841-848,8
中央引导地方科技发展资金项目—全省空气动力装备智能制造重点实验室建设(No.2025ZY01027).
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