氧化钠含量对赤泥基地聚合物同步注浆浆液性能影响分析OA
Effects of Sodium Oxide Content on the Performance of Red Mud-Based Geopolymer for Tail Grouting
[目的]针对赤泥基地聚合物同步注浆材料的性能优化问题,探讨氧化钠含量对浆液新鲜状态性能、硬化后力学性能、电学特性及微观结构的影响.[方法]通过单因素试验设计,以氧化钠含量(0%~8%)为变量,系统分析浆液的密度、流动度、稠度、结石率、泌水率、凝结时间、无侧限抗压强度、电阻率、电化学性能及微观形貌特征.[结果]结果表明:随着氧化钠的增加,浆液密度逐渐增大,流动度降低,浆液趋于黏稠,凝结时间明显缩短;抗压强度呈指数增长趋势,含量在5%~8%时显著提升,28 d龄期强度最高达60.64 MPa;电阻率随氧化钠含量增加而升高,长期养护进一步提高材料的微观致密性;电化学测试显示,高氧化钠含量促进聚合反应产物生成,提高材料耐久性;扫描电子显微镜(SEM)测试结果表明,氧化钠含量的增加使材料由疏松多孔逐渐转变为致密均匀结构,其中5%~8%含量试样表现出最佳微观特性;总结得出氧化钠含量在5%~7%时可优化浆液性能,兼顾施工性与力学耐久性.
[Purposes]To optimize the performance of red mud-based geopolymer for tail grout-ing,the effects of Na2O content on the fresh properties,hardened mechanical properties,electrical characteristics,and microstructure of the slurry are investigated in this study.[Methods]A single-fac-tor experimental design was employed,with Na2O content(0~8%)as the variable,to systematically analyze the slurry's density,fluidity,consistency,stone rate,bleeding rate,setting time,unconfined compressive strength,resistivity,electrochemical properties,and microscopic morphology.[Results]The results indicate that as the Na2O content increases,the slurry density gradually increases,fluidity decreases,the slurry becomes more viscous,and the setting time is significantly shortened.The com-pressive strength exhibits an exponential growth trend,with a significant increase at 5%~8%Na2O content,reaching a maximum of 60.64 MPa at 28 d.Resistivity increases with Na2O content,and long-term curing further enhances the material's microstructural compactness.Electrochemical tests show that higher Na2O content promotes the formation of geopolymerization products,improving ma-terial durability.Scanning electron microscope analyses reveal that increasing Na2O content transforms the material from a porous and loose structure to a dense and uniform one,with the 5%~8%content samples exhibiting the most favorable microstructural characteristics.In summary,Na2O content in the range of 5%~7%optimizes slurry performance,balancing workability and mechanical durability.
赵晨浩;梁家馨;董晓强;刘维;杨振
太原理工大学 土木工程学院,山西 太原太原理工大学 土木工程学院,山西 太原太原理工大学 土木工程学院,山西 太原||山西省土木工程防灾与控制重点实验室,山西 太原苏州大学 轨道交通学院,江苏 苏州太原理工大学 土木工程学院,山西 太原
建筑与水利
赤泥基地聚合物同步注浆氧化钠浆液性能电学特性
red mud-based geopolymertail groutingsodium oxideslurry performanceelectrical characteristics
《太原理工大学学报》 2026 (4)
738-748,11
国家自然科学基金(52378360,51978438)山西省基础研究计划青年项目(202403021212155)山西省高等学校科技创新计划(2024L044)
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