首页|期刊导航|泥沙研究|基于Zeta电位及微观形态的极细石英质粉砂絮凝特性研究

基于Zeta电位及微观形态的极细石英质粉砂絮凝特性研究OA

Study on the flocculation characteristics of ultrafine quartz silt based on Zeta potential and micromorphology

中文摘要英文摘要

细颗粒泥沙絮凝影响其输移与岸滩演变,研究细颗粒泥沙的絮凝特性与机理具有重要意义.选取极细石英质粉砂作为典型非黏土矿物,以高岭土作为典型黏土矿物对照组,通过分析两种样本的级配、微观形态及其在不同浓度的NaCl与CaCl2溶液中Zeta电位变化,研究石英质粉砂颗粒的絮凝特性.研究发现,极细石英质粉砂在清水中可发生絮凝,并以细颗粒聚合为主要絮凝形式.随着电解质溶液浓度升高,两种矿物颗粒表面Zeta电位均先陡增、后波动,但二者波动中心与幅度存在差异.粒径小于8 μm的非黏土矿物组分絮凝后,其絮团电位随电解质浓度的变化趋势及级配参数与黏土矿物类似,建议对此类非黏土矿物泥沙颗粒采用黏性沙理论计算絮团尺寸与沉速.

The flocculation of fine-grained sediment significantly influences their transport behavior and coastal evolution,making it essential to understand their flocculation characteristics and underlying mechanisms.In this study,ultrafine quartz silt was selected as a representative non-clay mineral,with kaolinite serving as a typical clay mineral for comparison.The flocculation behavior of quartz silt particles was investigated by analy-zing the grain size distribution,microscopic morphology,and Zeta potential variations of both samples in NaCl and CaCl2 solutions with varying concentrations.Results indicate that ultrafine quartz silt can flocculate in freshwater,primarily through the aggregation of fine particles.As electrolyte concentration increases,the Zeta potentials of both minerals exhibit an initial sharp increase followed by fluctuations around a stable value.However,the fluctuation centers and amplitudes differ between the two samples.The trend of floc Zeta poten-tial and gradation parameters of non-clay mineral components of particle size less than 8 μm with variation of e-lectrolyte concentration are similar to those of clay minerals.It is suggested that cohesive sediment theory can be applied to estimate floc size and settling velocity for non-clay particles smaller than 8 μm.

姚鹏;赵欣;董嘉威;王远;苏敏

河海大学水灾害防御全国重点实验室,江苏南京 210098||自然资源部华东海岸带野外科学观测研究站,江苏南京 210098||河海大学港口海岸与近海工程学院,江苏南京 210098河海大学港口海岸与近海工程学院,江苏南京 210098河海大学港口海岸与近海工程学院,江苏南京 210098河海大学港口海岸与近海工程学院,江苏南京 210098自然资源部华东海岸带野外科学观测研究站,江苏南京 210098||河海大学港口海岸与近海工程学院,江苏南京 210098

建筑与水利

石英砂高岭土絮凝特性Zeta电位微观形态

quartz siltkaoliniteflocculation characteristicsZeta potentialmicromorphology

《泥沙研究》 2026 (3)

1-8,8

国家重点研发计划项目(2023YFC3008100)国家自然科学基金项目(42476166)江苏省自然资源科技创新项目(JSZRKJ202402)自然资源部华东海岸带野外科学观测研究站开放课题(ORSECCZ2025101)

10.16239/j.cnki.0468-155x.2026.03.001

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