赤泥基复合水化晶种对硅酸盐水泥砂浆性能的影响OA
Effects of Red Mud-Based Composite Hydration Seeds on Properties of Portland Cement Mortar
为提升赤泥在水泥基材料中的高效资源化利用,本研究采用酸浸预处理结合水热合成的方法制备了赤泥基复合水化晶种(RM-CAW),并将其掺入水泥砂浆中,系统研究其对水泥水化反应、微观结构及力学性能的影响.通过力学性能测试及X射线衍射(XRD)、热重分析(TG)、扫描电子显微镜(SEM)、比表面积及孔径分析等表征手段,对RM-CAW的增强机制进行了探讨.结果表明,掺入RM-CAW的水泥砂浆在7和28 d均表现出更优的力学性能,其中掺入5.0%(质量分数)RM-CAW的砂浆(HARM-5.0)28 d抗折强度和抗压强度较基准水泥砂浆分别提高11.1%和6.9%.RM-CAW的引入促进了水化硅酸钙(C-S-H)等水化产物的生成,显著改善了界面过渡区结构并提高了体系致密性,促进了孔隙细化与大孔比例降低.
To enhance the efficient resource utilization of red mud in cement-based materials,this study prepared red mud-based composite hydration seeds(RM-CAW)via acid leaching pretreatment combined with hydrothermal synthesis,and incorporated them into cement mortar to systematically investigate their effects on cement hydration behavior,microstructure,and mechanical properties.Mechanical performance tests together with X-ray diffraction(XRD),thermogravimetric analysis(TG),scanning electron microscopy(SEM),and specific surface area and pore size distribution analyses were conducted to elucidate the strengthening mechanism of RM-CAW.The results indicate that the incorporation of RM-CAW significantly improves the mechanical properties of cement mortar at both 7 and 28 d.In particular,compared with reference cement mortar,the mortar with 5.0%(mass fraction)RM-CAW(HARM-5.0)specimen exhibits increases of 11.1%and 6.9%in flexural strength and compressive strength at 28 d,respectively.The addition of RM-CAW promotes the formation of hydration products such as calcium silicate hydrate(C-S-H),has a pronounced improvement in the interfacial transition zone and an overall densification of the matrix,and promotes pore structure refinement and a reduction in the proportion of large pores.
李富云;黄胜晶;焦威力;邓孝炜;陈春恒;韦驰;赖芳;李晶
广西大学化学化工学院,南宁 530004广西大学化学化工学院,南宁 530004广西大学化学化工学院,南宁 530004广西大学化学化工学院,南宁 530004广西大学化学化工学院,南宁 530004广西大学化学化工学院,南宁 530004广西大学化学化工学院,南宁 530004广西大学化学化工学院,南宁 530004||广西零碳智能化重点实验室,南宁 530004||广西高校低碳绿色化工新技术重点实验室,南宁 530004
化学化工
赤泥赤泥基复合水化晶种普通硅酸盐水泥腐殖酸水热合成资源化利用
red mudred mud-based composite hydration seedordinary Portland cementhumic acidhydrothermal synthesisresource utilization
《硅酸盐通报》 2026 (7)
2237-2249,13
"大学生创新创业训练计划"项目(S202410593112)广西自然科学基金会(2025GXNSFDA069049)
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