双陶瓷热障涂层的表面改性与性能研究OA
Surface Modification and Performance Study of Dual Ceramic Thermal Barrier Coatings
本研究提出的镀铝LaMA双陶瓷热障涂层延寿策略通过在LaMA涂层表面镀铝显著提升了涂层的耐高温氧化性能.通过等离子喷涂与电弧离子镀复合技术制备涂层,并采用X射线衍射(XRD)、扫描电子显微镜(SEM)和能谱分析(EDS)对涂层的物相、表面形貌及断面结构进行了详细表征.研究发现,镀铝处理能够显著减少涂层表面的微裂纹和孔隙,提高涂层的致密性,增强其抗氧化性能.在氧化动力学测试中,镀铝LaMA涂层的氧化增重速率为4.84±0.23 mg/cm2,显著低于未镀铝涂层的8.39±0.12 mg/cm2,表明镀铝层有效降低了高温环境下的氧化增重.进一步分析TGO层的演化,结果显示,镀铝涂层能够有效延缓TGO层的快速增厚,减缓氧化过程中界面应力的积累,表明镀铝处理在提高涂层高温抗氧化性能方面具有重要优势.这些发现为双陶瓷热障涂层在高温环境中的长期可靠性提供了有效的技术解决方案.
The proposed aluminum-plated LaMA dual ceramic thermal barrier coating life extension strategy significantly enhances the coating's high-temperature oxidation resistance through aluminum deposition on the LaMA coating surface.The coating was fabricated using a composite technique of plasma spraying and arc ion plating.Detailed characterization of the coating's phase composition,surface morphology,and cross-sectional structure was performed via X-ray diffraction(XRD),scanning electron microscopy(SEM),and energy-dispersive X-ray spectroscopy(EDS).Findings revealed that the aluminum plating treatment significantly reduced microcracks and pores on the coating surface,improved coating density,and enhanced oxidation resistance.In oxidation kinetics testing,the weight gain rate of the aluminum-coated LaMA coating was 4.84±0.23 mg/cm2,significantly lower than the 8.39±0.12 mg/cm2 of the uncoated sample,indicating that the aluminum layer effectively reduced weight gain under high-temperature oxidation.Further analysis of TGO layer evolution revealed that the aluminum-coated layer effectively retards rapid TGO thickening and mitigates interfacial stress accumulation during oxidation.This demonstrates the significant advantage of aluminum coating in enhancing high-temperature oxidation resistance.These findings provide an effective technical solution for ensuring the long-term reliability of dual-ceramic thermal barrier coatings in high-temperature environments.
岳纺宇;宁浩楠;刘莹;郭亚楠;王岭
营口理工学院材料科学与工程学院,辽宁 营口 115000营口理工学院材料科学与工程学院,辽宁 营口 115000营口理工学院材料科学与工程学院,辽宁 营口 115000营口理工学院材料科学与工程学院,辽宁 营口 115000营口理工学院材料科学与工程学院,辽宁 营口 115000
化学化工
镀铝LaMA涂层高温氧化双陶瓷热障涂层
Aluminum coatingLaMA coatingHigh-temperature oxidationDual-ceramic thermal barrier coating
《现代技术陶瓷》 2026 (3)
272-279,8
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