全陶瓷微封装燃料TRISO颗粒涂层力学及界面特性研究OA
Mechanical and Interfacial Bonding Properties of TRISO Coatings in Ceramic-Based Dispersed Matrix Fuel
陶瓷基弥散微封装燃料(CDM)利用SiC基体优异的导热性能和抗辐照性能等优势,在提高TRISO颗粒安全性的同时满足了核反应堆高温运行长期稳定性的需求.本文以模拟核芯CDM样品为实验材料,对嵌入其中的TRISO燃料颗粒涂层力学性能及其与SiC基体间界面的结合力开展了研究.首先通过微米压痕法测试了各包覆涂层的弹性模量和维氏硬度以及SiC涂层和SiC基体的断裂韧性.进一步,综合推出法、侧面压入法和有限元模拟对相关界面的结合力进行了评估,并通过微观结构表征对各涂层及界面处的裂纹扩展行为进行了观察分析.研究结果表明,考虑CDM样品各界面的结合力以及各涂层区域本身的强度,较为疏松的Buffer层以及结合较弱的核芯/Buffer界面更易于发生破坏和失效.研究为燃料微球包覆涂层力学性能及界面结合力表征提出了可行的测试手段及分析方法,为TRISO及CDM样品制程工艺的改进提供了参考.
Ceramic-based dispersed matrix fuel(CDM)takes advantage of the excellent thermal conductivity and irradiation resistance of SiC materials,which can further enhance the operational safety of TRISO(Tristructural-isotropic)pellets and meet the requirements of higher temperatures and fuel consumption in reactors.In this work,the mechanical properties of the TRISO pellets coating and its interfacial bonding properties with the SiC matrix in CDM with zirconia simulated core were studied.The Young's modulus and Vickers' hardness of each coating,as well as the fracture toughness of the SiC coating and the SiC substrate,were tested by the micrometer indentation method.Furthermore,the bonding force of the relevant interfaces was evaluated by using the push-out method and the indentation method,and the crack propagation behavior at each coating and interface was investigated with microstructure characterization.The results show that considering the bonding force of each interface of the CDM sample and the strength of each coating area itself,the relatively loose Buffer layer and the core/Buffer interface with weak bonding are prone to damage and failure.The study has proposed feasible testing methods and analytical approaches for the characterization of the mechanical properties and interfacial bonding of fuel microsphere-coated coatings,providing an important reference for the improvement of the sample processing technology of TRISO and CDM.
翟晟业;张鹏;李统业;王凯;倪娜;李垣明;何宗倍
上海交通大学材料科学与工程学院,上海 200240上海大学材料科学与工程学院,上海 200072中国核动力设计研究院核燃料元件及材料研究所,成都 610213中国核动力设计研究院核燃料元件及材料研究所,成都 610213上海交通大学机械动力与工程学院,上海 200240中国核动力设计研究院核反应堆技术全国重点实验室,成都 610213中国核动力设计研究院核燃料元件及材料研究所,成都 610213
化学化工
TRISO微球CDM热解碳微观结构力学性能界面结合力
TRISO microsphereCDMPyrolytic carbonMicrostructureMechanical propertiesInterfacial bonding
《现代技术陶瓷》 2026 (3)
256-271,16
国家自然科学基金资助项目(U20B2013)四川省自然科学基金项目(2024NSFJQ003)中核集团基础研究项目(CNNC-JCYJ-202218).National Natural Science Foundation of China(U20B2013)Natural Science Foundation of Sichuan Province(2024NSFJQ003)China National Nuclear Corporation Basic Research Project(CNNC-JCYJ-202218).
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