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陕北特低渗储层注水井序列化复合解堵体系OA

A study on a sequential composite plugging removal system for water injection wells in ultra-low permeability reservoirs,Northern Shaanxi

中文摘要英文摘要

针对陕北特低渗储层注水井因无机垢沉积与微生物生物膜/有机质复合堵塞导致的注水压力骤升难题,创新提出序列化复合解堵技术.通过 XRD、FTIR、SEM-EDS等多尺度表征明确堵塞物组成为有机-无机复合结构,有机与无机组分比1∶9,其中 SRB生物膜多糖-蛋白质网络包裹无机垢形成致密屏障,导致常规解堵剂失效.基于此,构建三段式协同解堵体系并阐明其分级解堵机理:首段生物膜破除,采用 0.03%季铵盐杀菌剂 JY-1+0.4%~0.5%生物膜剥离剂(淀粉酶与蛋白酶质量比为 1∶1),酶解多糖骨架与蛋白基质,破除生物膜物理屏障;次段无机垢溶蚀,采用 3.0%EDTMP螯合剂+3%HCl+0.8%柠檬酸钠,选择性溶解 CaCO3/FeS并抑制二次沉淀;末段助排防伤,采用 0.4%氟碳表面活性剂 FT-1+1%异丙醇+0.5%咪唑啉缓蚀剂 ML-1,通过降低界面张力促进残渣返排,同时咪唑啉在管壁形成吸附膜抑制腐蚀.室内实验表明,该体系溶蚀率达 92.3%,腐蚀速率仅 0.047 mm/a,防膨率与除铁率均高于 84%,其溶蚀率显著优于传统土酸(45.2%)及螯合酸(65.1%)体系.现场试验中,注水压力从 15 MPa降至 2.0 MPa,有效期超 6个月.该技术解决了该油区的注水井堵塞难题,为特低渗油田复合堵塞治理提供了高效、低伤害的新路径.

To address the challenge of a sudden surge in water injection pressure caused by composite plugging of inorganic scale deposition,microbial biofilms and organic substances in water injectors in ultra-low permeability reservoirs in northern Shaanxi,this study innovatively proposes a mild sequential composite plugging removal technology.Through multi-scale characterization such as XRD,FTIR,and SEM-EDS,the plugging material is identified as an organic-inorganic composite structure with a ratio of 1∶9,among which the polysaccharide-protein network of SRB(Sulfate-Reducing Bacteria)biofilms wraps around inorganic scales to form a dense barrier,resulting in the failure of conventional plugging removers.Based on this,a three-stage synergistic plugging removal system is constructed and its graded plugging removal mechanism is clarified.The first stage is biofilm breakdown:0.03%quaternary ammonium salt bactericide JY-1 and 0.4%-0.5%biofilm stripper(mass ratio of amylase to protease is 1∶1)is engaged,which breaks the physical barrier of biofilms through the enzymatic degradation of polysaccharide skeletons and protein matrices.The second stage is inorganic scale dissolution:3.0%EDTMP chelating agent,3%HCl,and 0.8%sodium citrate is engaged,which selectively dissolves CaCO3/FeS and inhibits secondary precipitation.The third stage is flowback assistance and formation damage prevention:0.4%fluorocarbon surfactant FT-1,1%isopropanol,and 0.5%imidazoline corrosion inhibitor ML-1 is engaged,which promotes the flowback of residues by reducing interfacial tension force,while the imidazoline forms an adsorption film on the pipe walls to inhibit corrosion.Laboratory-scale experiments show that this system achieves a dissolution rate of 92.3%,a corrosion rate of 0.047 mm/a,and both the anti-swelling rate and iron removal rate exceed 84%.This system is significantly superior to the traditional mud acid(45.2%)and chelating acid(65.1%)systems in terms of dissolution rate.In field tests,the water injection pressure decreased from 15 MPa to 2.0 MPa,with an effective period of more than 6 months.This technology solves the plugging challenges of water injectors in this oil area and provides an efficient and low-damage approach for the treatment of composite plugging in ultra-low permeability oilfields.

齐宏鹏;毛慧;夏宇;唐善法

延长油田股份有限公司吴起采油厂,陕西 延安 716000中国石油集团安全环保技术研究院有限公司,北京 102206长江大学石油工程学院,湖北 武汉 430100长江大学石油工程学院,湖北 武汉 430100

能源科技

特低渗储层注水井复合堵塞序列化解堵生物膜剥离剂螯合酸解堵机理

ultra-low permeability reservoirwater injection wellcomposite pluggingsequential plugging removalbiofilm stripping agentchelating acidplugging removal mechanism

《石油钻采工艺》 2026 (3)

370-377,8

延长油田股份有限公司新技术项目"油田精细注水配套工艺技术研究与试验"(编号:ycsy2023xjs-C-01).

10.13639/j.odpt.202509001

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