高效节能碳捕集溶剂与工艺研究OA
Study on high-efficiency and energy-saving carbon capture solvent and process
目的 针对胺法碳捕集技术存在的再生能耗高与溶剂降解问题,研究高效节能的吸收溶剂及其配套工艺,以降低运行成本.方法 ①通过分析不同溶剂的反应机理与能耗特性,研发了多元复合溶剂 CT8-23B;②引入 pH 调控辅助再生工艺,利用弱酸盐构建缓冲体系以加速解吸;③评估了级间冷却、机械蒸汽再压缩等工艺的节能效果.结果 与质量分数为30%的 MEA相比,CT8-23B溶剂的 CO2 吸收速率相当,饱和吸收容量提高 27%,解吸速率提升 100%,再生能耗降低约 30%;pH 调控辅助再生工艺可进一步强化再生过程,降低能耗.结论 CT8-23B溶剂与 pH调控辅助再生等节能工艺相结合,可显著降低碳捕集工艺的能耗,且具备良好的工业应用与改造潜力,提供了一种低成本的碳捕集技术方案.
Objective To address the issues of high regeneration energy consumption and solvent degradation in amine carbon capture technology,an efficient and energy-saving absorption solvent and its corresponding process were studied to reduce operating costs.Method First,by analyzing the reaction mechanisms and energy consumption characteristics of different solvents,a multi-component composite solvent,CT8-23B,was developed.Second,a pH-regulation-assisted regeneration process was introduced,in which a weak-acid salt was used to establish a buffer system to accelerate desorption.Third,the energy-saving performance of interstage cooling,mechanical vapor recompression,and other processes was evaluated.Result Compared with 30 wt%MEA,the CT8-23B solvent exhibited a comparable CO2 absorption rate.In addition,the saturated absorption capacity was increased by 27%,the desorption rate was increased by 100%,and the regeneration energy consumption was reduced by about 30%.Furthermore,the pH-regulation-assisted regeneration process can further enhance the regeneration performance and reduce energy consumption.Conclusion The combination of the CT8-23B solvent with energy-saving processes such as the pH-regulation-assisted regeneration process can significantly reduce the energy consumption of the carbon capture process,and has good industrial application and retrofit potential,providing a low-cost carbon capture technology solution.
李雅欣;蒋巍;张雪莹;彭修军;刘可;刘陶然;杨鹏
中国石油西南油气田公司天然气研究院中国石油西南油气田公司天然气研究院中国石油西南油气田公司重庆气矿中国石油西南油气田公司天然气研究院中国石油西南油气田公司天然气研究院中国石油石油化工研究院中国石油青海油田格尔木炼油厂
碳捕集混合胺溶剂CT8-23B贫水吸收剂氨基酸盐节能工艺
carbon captureblended amine solventsCT8-23Bwater-lean solventsamino acid saltsenergy-saving process
《石油与天然气化工》 2026 (3)
1-9,9
中国石油油气与新能源公司科技项目"西南卧龙河气田茅口组气藏CCUS-EGR先导性试验"(2023YQX10503ZK)
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