基于8年氢气输送服役条件的L245NS冷弯管与母管氢脆敏感性对比OA
Comparative Analysis of Hydrogen Embrittlement Susceptibility in Cold-bent Pipes and Straight Pipes of L245NS Pipeline Steel under Eight-year Hydrogen Transportation Service Conditions
为评估氢输运管道长期服役的可靠性,研究服役8年的L245NS管线钢冷弯管与母管的氢脆行为.通过慢应变变速率拉伸、金相观察、透射电子显微镜及电子背散射衍射等手段开展对比分析.结果表明,两者强度无显著差异,但冷弯管氢脆敏感指数(HEI=6.1%)显著高于母管,表明其氢脆风险更高.微观机制显示,母管为轧制态铁素体-珠光体组织(晶粒等轴直径为18 μm),位错密度低,小角度晶界(2~5°)长度1 960 μm,富含Σ13/Σ15等低能重合位置点阵(CSL)晶界,氢陷阱少,抑制氢聚集;冷弯管经塑性变形后(晶粒短轴直径为15 μm),晶粒拉长,位错增殖形成缠结与网络,小角度晶界增至3 000 μm,低能Σ晶界比例下降,产生大量氢捕获位点.断口分析显示,母管韧窝大而深,断口较平坦;冷弯管因加工硬化导致塑性下降,韧窝细小浅平,颈缩明显,脆性倾向增强.研究表明,冷加工显著"放大"L245NS钢的氢脆敏感性.研究结果为氢管道冷弯段的工艺优化和在役安全监测提供定量参考依据.
To evaluate the long-term reliability of hydrogen transportation pipelines,the hydrogen embrittlement behavior of cold-bent pipes and straight pipes for L245NS pipeline steel after eight years of service was investigated.A comparative analysis was conducted using slow strain rate testing,metallography,transmission electron microscopy,and electron backscatter diffraction.Results show no significant difference in strength between the two;however,the cold-bent pipe exhibits a higher hydrogen embrittlement susceptibility index(HEI=6.1%),indicating greater hydrogen embrittlement risk.Microstructural analysis reveals that the straight pipe has a rolled ferrite-pearlite structure with an equiaxed grain size of 18 μm,low dislocation density,small-angle grain boundaries(2~5°)totaling 1 960 μm in length,and abundant low-energy coincidence site lattice(CSL)boundaries such as Σ13 and Σ15,resulting in fewer hydrogen traps and suppressed hydrogen aggregation.In contrast,after plastic deformation,the cold-bent pipe shows elongated grains with the minor-axis grain diameter of 15 μm,increased dislocation density forming tangles and networks,small-angle grain boundary length increased to 3 000 μm,and reduced fraction of low-energy Σ boundaries—generating numerous hydrogen trapping sites and promoting hydrogen enrichment.Fractography shows the straight pipe has large,deep dimples and a relatively flat fracture surface,while the cold-bent pipe exhibits fine,shallow dimples and pronounced necking due to strain hardening-induced ductility loss,indicating increased brittleness.The research results demonstrates that cold working significantly amplifies the hydrogen embrittlement susceptibility of L245NS steel,providing quantitative guidance for process optimization and in-service monitoring of cold-bent pipeline sections.
王旭;赵立前;李硕;李国辉;陈祥;霍玉香
清华大学 材料学院,北京 100084中国石油管道工程有限公司,河北 廊坊 065000中国石油管道工程有限公司,河北 廊坊 065000中国石油管道工程有限公司,河北 廊坊 065000清华大学 材料学院,北京 100084||清华大学 先进成形制造教育部重点实验室,北京 100084敬业集团有限公司,石家庄 050409
矿业与冶金
L245NS管线钢氢脆冷弯管慢拉伸8年氢输服役低能Σ晶界位错增殖
L245NS pipeline steelhydrogen embrittlementcold-bent pipeslow strain rate testingeight-year hydrogen transportation servicelow-energy Σ grain boundariesdislocation multiplication
《焊管》 2026 (6)
39-49,11
中国石油管道工程有限公司项目"纯氢管线钢、环焊缝等相关性能氢损伤影响分析及评价研究"(项目编号2024-22)内蒙古自治区科技重大专项"中低压纯氢与掺氢燃气管道输送及应用关键技术研发"(项目编号2021SZD0082).
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