基于油水相分离的多孔环氧树脂制备及闪络强度提升机理OA
Preparation of Porous Epoxy Resin Based on Oil-water Phase Separation and Mechanism of Flashover Strength Enhancement
沿面闪络问题是制约电力设备可靠运行的关键瓶颈.多孔结构是提升闪络强度的有效方法,但现有多孔结构构造方法难以用于传统环氧树脂等绝缘材料.该文通过热固化结合油水相分离法制备多孔环氧树脂绝缘材料,利用悬浮水滴在环氧树脂中构造孔隙结构,通过调控水相含量(5%~40%)调控环氧基体的多孔形貌,分析了孔隙对材料疏水性及闪络强度的影响,结合电位衰减、电位扫描与放电路径观测揭示了多孔结构对闪络强度的作用机理.结果表明:当制孔剂(水)含量为10%~20%时,闪络强度提升效果最优,较无孔材料最高提升24.8%,多孔结构对沿面闪络强度的提升,可归因于孔隙促进表面电荷耗散与电晕稳定化的共同作用.
Surface flashover is a critical bottleneck restricting the reliable operation of electrical equipment.Although porous structures have proven effective in enhancing flashover strength,existing construction methods are difficult to ap-ply to traditional insulating materials like epoxy resin.We successfully prepared porous epoxy resin insulation materials through thermal curing combined with an oil-water phase separation method.Porous structure in epoxy resin is con-structed by the suspended water droplets.By adjusting the water phase content(5%~40%),we regulated the porous morphology of the epoxy matrix and analyzed the influence of pores on material hydrophobicity and flashover strength.Through potential decay analysis,potential scanning,and discharge path observation,the mechanism of porous structure in enhancing flashover strength is revealed.The results indicate that,when the pore-forming agent(water)content reaches 10%~20%,the flashover strength improvement is optimal,showing a maximum enhancement of 24.8%compared to non-porous materials.The enhancement can be attributed to the combined effects of pore-induced surface charge dissipa-tion and corona stabilization.
任杰睿;朱明晓;徐学凯;刘睿;罗禄洋;石博
中国石油大学(华东)新能源学院,青岛 266580中国石油大学(华东)新能源学院,青岛 266580中国石油大学(华东)新能源学院,青岛 266580中国石油大学(华东)新能源学院,青岛 266580中国石油大学(华东)新能源学院,青岛 266580中国石油大学(华东)新能源学院,青岛 266580
环氧树脂多孔结构沿面闪络疏水性电荷输运调控
epoxy resinporous structuresurface flashoverhydrophobicitycharge transport regulation
《高电压技术》 2026 (5)
2282-2290,9
山东省自然科学基金(ZR2021ME027)青岛市自然科学基金(24-4-4-zrjj-172-jch).Project supported by Natural Science Foundation of Shandong Province of China(ZR2021ME027),Qingdao Natural Science Foundation(24-4-4-zrjj-172-jch).
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