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氧化锌基电工陶瓷复合材料的低碳冷烧结研究进展OA

Progress of Low-carbon Cold Sintering of Zinc Oxide-based Electroceramic Ceramic Composites

中文摘要英文摘要

传统的电工陶瓷材料通常需要在1 000 ℃以上高温条件下进行烧结制备.然而,高温烧结条件易导致功能陶瓷材料性能劣化,同时限制了陶瓷与其他材料(如聚合物、金属等)的复合应用.冷烧结工艺(cold sintering process,CSP)作为一种新兴的低碳烧结技术,可将陶瓷材料的致密化烧结温度降低到300 ℃以下,显著降低了制备过程中的能耗与碳排放,为新型电工陶瓷材料的研发和性能优化提供了新的技术手段.该文主要综述了典型的氧化锌(ZnO)基电工陶瓷及其复合材料的低碳冷烧结研究现状,介绍了 ZnO陶瓷的冷烧结致密化机理,着重分析了 ZnO压敏电阻、ZnO-聚合物、ZnO-二维材料、ZnO-金属等电工陶瓷复合材料的低碳冷烧结制备工艺,以及其表现出的良好电学、光学、力学性能和独特的超疏水、晶粒各向异性和"类开关特性"等性能.研究表明,冷烧结技术在ZnO基电工陶瓷及其复合材料中具有广阔的应用前景,也为其他新型电工陶瓷材料的开发和性能提升提供了新的思路和参考.

Conventional electroceramic materials are typically sintered at high temperatures above 1 000 ℃.However,such high-temperature sintering conditions often result in performance degradation of functional ceramics and restrict their compositing with other materials,such as polymers and metals.As an emerging low-temperature sintering technique,the cold sintering process(CSP)allows ceramic densification at temperatures below 300 ℃,significantly reducing ener-gy consumption and carbon emissions during manufacturing.This method provides a novel strategy for the development and performance optimization of advanced electroceramics.This paper mainly summarizes recent advances in cold sin-tering of zinc oxide(ZnO)based electroceramics and their composites.First,the densification mechanism of ZnO ceramics with CSP is discussed.Then,the low-temperature sintering processes for various electroceramic composites,in-cluding ZnO varistors,ZnO-polymer,ZnO based two-dimensional material composites,and ZnO-metal are analyzed.These materials exhibit excellent electrical,optical,and mechanical properties,along with unique features such as super-hydrophobicity,grain anisotropy,and switch-like behavior.The results indicate that CSP exhibits promising application in ZnO-based electroceramics and their composites,while also providing valuable insights into the design and performance enhancement of other advanced electroceramic materials.

廖瑞金;侯欣源;赵学童;康晟淋;王祺;张杰;任成君

输变电装备技术全国重点实验室(重庆大学电气工程学院),重庆 400044输变电装备技术全国重点实验室(重庆大学电气工程学院),重庆 400044输变电装备技术全国重点实验室(重庆大学电气工程学院),重庆 400044输变电装备技术全国重点实验室(重庆大学电气工程学院),重庆 400044输变电装备技术全国重点实验室(重庆大学电气工程学院),重庆 400044国家电网有限公司西南分部,成都 610041国家电网有限公司西南分部,成都 610041

冷烧结工艺氧化锌复合材料碳排放电工陶瓷

cold sintering processzinc oxidecompositescarbon emissionselectroceramic materials

《高电压技术》 2026 (5)

2224-2239,16

国家电网有限公司科技项目(5500-202399372A-2-2-ZB).Project supported by Science and Technology Project of SGCC(5500-202399372A-2-2-ZB).

10.13336/j.1003-6520.hve.20251053

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