酸溶液对原状黄土一维变形和微观结构影响的试验研究OA
EXPERIMENTAL STUDY FOR THE EFFECTS OF ACID SOLUTION ON THE ONE-DIMENSIONAL DEFORMATION AND MICROSTRUCTURE OF INTACT LOESS
开展了不同浓度硫酸溶液污染原状黄土的一维非饱和压缩和湿陷试验,采用SEM和EDS对微观结构和颗粒矿物元素进行分析,揭示酸污染对非饱和原状黄土变形影响机理.结果表明:0.05 mol·L-1和0.5 mol·L-1酸污染试样在不同吸力下的屈服应力较未污染试样分别增大和减小.这是因为黄土中的黏土矿物絮凝化在低浓度酸污染时起主导作用,而胶结矿物溶解在高浓度酸污染时占主导地位.另一方面,给定吸力下原状黄土结构允许空间随酸浓度增加而减小.这是由于酸污染导致重塑试样压缩指数增大和原状试样中胶结矿物溶解.此外,未污染和0.05 mol·L-1酸污染试样的测试湿陷系数和计算湿陷系数一致性较好,而0.5 mol·L-1酸污染试样的测试湿陷系数偏离计算湿陷系数.这可能是因为后者在湿陷时孔隙溶液离子浓度降低较为明显.
This research investigates one-dimensional unsaturated compression and collapse of intact loess conta-minated with different concentrations of sulfuric acid solution.The microstructure and mineral composition were analyzed using SEM and SEM-EDS to reveal the mechanism of acid pollution on the deformation of unsaturated loess.The results showed that the yield stress of 0.05 mol·L-1 and 0.5 mol·L-1 acid-contaminated loess increased and decreased,respectively,compared to the uncontaminated loess under different suctions.This is because the flocculation of clay in loess plays a dominant role at low-concentration acid pollution,while the dissolution of cementing minerals dominates at high-concentration acid pollution.On the other hand,the permissible void space of the soil structure decreased as the acid concentration increased under a given suction.This is due to the increase in the compression index of the remolded samples and the dissolution of cementing minerals caused by acid pollution.In addition,the measured and calculated collapse potentials were in good agreement for the uncontaminated and 0.05 mol·L-1 acid-contaminated samples,while the measured values for the 0.5 mol·L-1 acid-contaminated sample deviated from the calculations.This may be because the concentration of pore ionic solution during collapse is significantly lower in the latter case.
张继文;穆青翼;薛明明;黄强兵;廖红建;薛伟;曹杰
机械工业勘察设计研究院有限公司,西安 710021,中国||陕西省特殊岩土性质与处理重点实验室,西安 710021,中国长安大学地质工程与测绘学院,西安 710061,中国||西部矿产资源与地质工程教育部重点实验室,西安 710061,中国长安大学地质工程与测绘学院,西安 710061,中国||西部矿产资源与地质工程教育部重点实验室,西安 710061,中国长安大学地质工程与测绘学院,西安 710061,中国||西部矿产资源与地质工程教育部重点实验室,西安 710061,中国西安交通大学土木工程系,西安 710049,中国西安交通大学土木工程系,西安 710049,中国机械工业勘察设计研究院有限公司,西安 710021,中国||陕西省特殊岩土性质与处理重点实验室,西安 710021,中国
建筑与水利
酸污染黄土微观结构吸力压缩变形湿陷变形
Acid-contaminated LoessMicro-structureSuctionCompressibilityCollapsibility
《工程地质学报》 2026 (3)
933-944,12
国家自然科学基金项目(资助号:52279109),国家重点研发计划项目(资助号:2023YFC3008404).This research is supported by the National Natural Science Foundation of China(Grant No.52279109)and the National Key R&D Program of China(Grant No.2023YFC3008404).
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