首页|期刊导航|分析化学|MXene增强型导电水凝胶的快速制备及其在柔性可穿戴传感器中的应用

MXene增强型导电水凝胶的快速制备及其在柔性可穿戴传感器中的应用OA

Rapid Preparation of MXene-Reinforced Conductive Hydrogels and Its Application in Flexible Wearable Sensors

中文摘要英文摘要

针对柔性可穿戴传感器基体材料制备时间长、难以同时响应大幅形变和微弱刺激等问题,本研究构建了由聚乙烯醇(PVA)、单宁酸(TA)和MXene纳米片组成的导电水凝胶.此水凝胶在室温下通过简单物理混合即可在10~30 s内成胶.通过流变测试、电学测试和扫描电子显微镜表征了其力学性能、导电性能和微观结构,并通过损伤-修复实验考察了其自修复行为.结果表明,此水凝胶的断裂伸长率超过600%,10 s内可实现自修复,电导率可达到0.513 S/m.引入MXene促进了连续导电网络形成,使材料既能对手指弯曲和肌肉收缩等大幅度运动产生稳定的电信号,也能对吹气和水滴冲击等微弱刺激产生可分辨响应.此水凝胶具有可快速制备、较好的力学性能、导电性能和跨尺度传感能力,可用于柔性可穿戴传感器.

To address the issues of long preparation time and the difficulty of simultaneously responding to large-scale deformation and micro-scale stimulation for matrix materials of flexible wearable sensors,this study constructed a conductive hydrogel composed of polyvinyl alcohol(PVA),tannic acid(TA),and MXene nanosheets.The hydrogel could gel within 10-30 s at room temperature by simple physical mixing.The mechanical properties,electrical conductivity,and microstructure were characterized by rheological tests,electrical measurements,and scanning electron microscopy,while the self-healing behavior was investigated through damage-repair experiments.The results showed that the hydrogel exhibited an elongation at break exceeding 600%,achieved self-healing within 10 s,and attained an electrical conductivity of up to 0.513 S/m.The introduction of MXene promoted the formation of a continuous conductive network,enabling the material to generate stable electrical signals in response to large-scale deformation such as finger bending and muscle contraction,as well as distinguishable responses to micro-scale stimulation including blowing and water droplet impact.This hydrogel combined rapid preparation,favorable mechanical properties,electrical conductivity,and cross-scale sensing capability,making it suitable for flexible wearable sensors.

蔺意轩;柳越;汤健;马崇博

东北师范大学化学学院,多酸与网状材料化学教育部重点实验室,动力电池国家地方联合工程实验室,纳米生物传感分析吉林省高校重点实验室,分析测试中心,长春 130024东北师范大学化学学院,多酸与网状材料化学教育部重点实验室,动力电池国家地方联合工程实验室,纳米生物传感分析吉林省高校重点实验室,分析测试中心,长春 130024中国科学院长春应用化学研究所,高分子科学与技术全国重点实验室,长春 130022东北师范大学化学学院,多酸与网状材料化学教育部重点实验室,动力电池国家地方联合工程实验室,纳米生物传感分析吉林省高校重点实验室,分析测试中心,长春 130024

导电水凝胶聚乙烯醇单宁酸MXene可穿戴应变传感器

Conductive hydrogelPolyvinyl alcoholTannic acidMXeneWearable strain sensor

《分析化学》 2026 (6)

994-1003,中插1-中插8,18

吉林省科技厅科技发展计划项目(国际科技合作项目,No.20250205057GH)和东北师范大学分析测试中心资助. Supported by the Science and Technology Development Program of Jilin Provincial Department of Science and Technology(International Science and Technology Cooperation Program,No.20250205057GH)and the Analysis and Testing Center of Northeast Normal University.

10.19756/j.issn.0253-3820.251353

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