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传输方向可重构的行波无损离子操纵结构OA

Reconfigurable Transmission Direction Travelling-Wave Structure for Lossless Ion Manipulation

中文摘要英文摘要

行波无损离子操纵结构(Travelling wave structures for lossless ion manipulations,TW-SLIM)采用行波电场驱动离子前进,可实现超长传输路径,在物质传输和分离方面具有广阔的应用前景.然而,传统的TW-SLIM在结构设计完成后其离子传输方向不可改变,显著限制了SLIM体系在复杂系统中的应用灵活性.针对上述问题,本研究提出了一种传输方向可重构的TW-SLIM结构(Reconfigurable transmission direction TW-SLIM structure,RTDTW-SLIM),通过对传统TW-SLIM中的保护电极、行波电极与射频电极进行功能融合与重新分配,实现了离子在多个方向的无损传输.同时,通过缩减保护电极尺寸,对整体结构进行了小型化设计,有利于系统集成.通过搭建RTDTW-SLIM实验平台,并以甲基膦酸二甲酯(DMMP)为目标分析物开展实验研究.结果表明,在平台最优电压配置条件下,离子在不同传输方向的传输效率均高于90%.本研究验证了RTDTW-SLIM在离子传输方向可重构方面的有效性,为其在离子迁移谱分析及多种离子分析系统联用中的应用提供了新的技术方案.

Travelling wave structures for lossless ion manipulations(TW-SLIM)utilize travelling wave electric fields to drive ions forward,enabling ultra-long ion transmission paths and holding broad application prospects in ion transport and separation.However,in conventional TW-SLIM designs,the ion transmission direction cannot be altered once the device is fabricated,significantly limiting the flexibility of SLIM-based systems in complex applications.To address this issue,this study proposed a reconfigurable transmission direction TW-SLIM structure(RTDTW-SLIM).By functionally integrating and redistributing the guard electrodes,travelling wave electrodes,and radio frequency(RF)electrod from the conventional TW-SLIM layout,this architecture achieved lossless ion transport in multiple directions.Furthermore,through a reduction in the size of the guard electrodes,the overall structure was miniaturized,facilitating system integration.An experimental platform for RTDTW-SLIM was constructed,and experiments were conducted using dimethyl methylphosphonate(DMMP)as the target analyte.The results demonstrated that under optimized voltage configurations,the ion transmission efficiency could exceed 90%in different transmission directions.These findings verified the effectiveness of RTDTW-SLIM in achieving reconfigurable ion transmission pathways and provided a novel technical approach for its application in ion mobility spectrometry and the coupling of diverse ion analysis systems.

查永毅;张允晶;张毅;陈炜多;王琳;李灵锋;李鹏

苏州大学电子信息学院,苏州 215006苏州大学电子信息学院,苏州 215006国网宁德供电公司,宁德 352100国网宁德供电公司,宁德 352100中国人民解放军32381部队,北京 100072苏州大学电子信息学院,苏州 215006||苏州微木智能系统有限公司,苏州 215163苏州大学电子信息学院,苏州 215006||苏州微木智能系统有限公司,苏州 215163

无损离子操纵结构离子迁移谱多向传输小分子物质分析

Lossless ion manipulation structureIon mobility spectrometryMulti-directional transmissionSmall molecule substances analysis

《分析化学》 2026 (6)

975-984,10

国家重点研发计划项目(No.2022YFC330090)资助. Supported by the National Key Research and Development Program of China(No.2022YFC3300900).

10.19756/j.issn.0253-3820.261041

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