首页|期刊导航|粉末冶金技术|激光粉末床熔融成形Al-Si-Fe-Mn-Ni-Sc-Zr合金的组织形貌及腐蚀行为

激光粉末床熔融成形Al-Si-Fe-Mn-Ni-Sc-Zr合金的组织形貌及腐蚀行为OA

Microstructure and corrosion behavior of Al-Si-Fe-Mn-Ni-Sc-Zr alloy processed by laser powder bed fusion

中文摘要英文摘要

为探讨添加不同质量分数Al-Mg-Sc-Zr合金对激光粉末床熔融(PBF-LB)成形Al-Si系合金组织及腐蚀行为的影响,向Al-Si-Fe-Mn-Ni(ASF)合金粉末中分别添加质量分数10%、20%、30%的Al-Mg-Sc-Zr粉末,通过激光粉末床熔融成形技术制备得到Al-Si-Fe-Mn-Ni-Sc-Zr(ASF-M)交叉合金(Cross-over alloy),并对比分析了 ASF-M合金的微观组织和耐腐蚀性能.结果表明,添加适量的Al-Mg-Sc-Zr合金可有效抑制ASF-M合金等轴晶区和柱状晶区晶粒的长大,细化等轴晶区α-Al晶粒和Si网络结构,并减小柱状晶区Si颗粒的尺寸(10~100 nm).电化学测试结果显示,ASF-M10合金相比于ASF-M0合金,表现出更高的阻抗、更低的腐蚀电流密度和优异的抗点蚀性能;而ASF-M20和ASF-M30合金的抗腐蚀性能则较ASF-M0合金有所下降.浸泡腐蚀形貌分析表明,随着Al-Mg-Sc-Zr合金的添加,ASF-M合金连续层间腐蚀被抑制,出现少量点蚀坑;主要是因为细化的Si网状组织可有效抑制电偶腐蚀,同时,Mg元素能够起到稳定氧化膜的作用.

To investigate the effects of adding different mass fractions of Al-Mg-Sc-Zr alloys on the microstructure and corrosion behavior of Al-Si alloy formed by powder bed fusion-laser beam(PBF-LB),10%,20%,and 30%mass fractions of Al-Mg-Sc-Zr powders were added to the Al-Si-Fe-Mn-Ni(ASF)alloy powder.The ASF-M cross-over alloy was fabricated through powder bed fusion-laser beam technology,and the microstructure and corrosion resistance of the ASF-M alloy were compared and analyzed.The results show that adding an appropriate amount of Al-Mg-Sc-Zr alloy can effectively inhibit the growth of grains in the equiaxed zone and columnar zone of the ASF-M alloy,refine the α-Al grains and Si network structure in the equiaxed zone,and reduce the size of Si particles in the columnar zone(10~100 nm).The electrochemical test results show that the ASF-M10 alloy exhibits higher impedance,lower corrosion current density,and superior pitting resistance compared to the ASF-M0 alloy;while the corrosion resistance of the ASF-M20 and ASF-M30 alloys is slightly lower than that of the ASF-M0 alloy.The analysis of immersion corrosion morphology indicates that with the addition of Al-Mg-Sc-Zr alloy,the interlayer corrosion of the continuous layer of ASF-M alloy is inhibited,and a few pitting corrosion pits appear;this is mainly because the refined Si reticular structure can effectively inhibit galvanic corrosion,and at the same time,the Mg element can play a role in stabilizing the oxide film.

郝宇;张利;杨晓辉;仪登豪;苏辉;李晓峰

中北大学材料科学与工程学院,太原 030051中北大学材料科学与工程学院,太原 030051太原科技大学分析测试中心,太原 030024中北大学材料科学与工程学院,太原 030051中北大学材料科学与工程学院,太原 030051中北大学材料科学与工程学院,太原 030051

矿业与冶金

激光粉末床熔融交叉合金组织演变电化学腐蚀性能腐蚀机理

powder bed fusion-laser beamcross-over alloymicrostructural evolutionelectrochemical corrosion propertiescorrosion mechanism

《粉末冶金技术》 2026 (3)

340-351,12

10.19591/j.cnki.cn11-1974/tf.2026010002

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