锌冶炼中浸渣低酸浸出铟实验研究OA
Experimental Study on Low-acid Leaching of Indium from Neutral Leach Residue in Zinc Smelting
在"双碳"目标背景下,有色金属冶炼过程固体废渣的资源化利用对实现行业绿色低碳发展具有重要意义.锌冶炼中性浸出渣中富集多种有价金属,其中铟的高效回收尤为关键.针对常压低酸浸出过程中铟浸出率偏低的问题,本文采用常压硫酸浸出工艺,以锌冶炼中浸渣为研究对象,系统考察了酸度、反应时间、氧化性气氛及还原性氛围等因素对铟浸出行为的影响规律.结果表明,在低酸浸出条件下,铟的浸出率随硫酸浓度和反应时间的增加而提高,但当氧化性气氛增强或反应时间过长时,铟浸出率反而下降.在硫酸浓度为 85 g/L、液固比为 4∶1、浸出温度为 85℃、反应时间为 5.5 h、锌精矿加入量为 5 g/L 的条件下,铟的浸出率可达 60.87%.研究结果为锌冶炼中浸渣在常压低酸条件下回收铟提供了可行的工艺依据.
Under the background of"dual carbon"goals,resource utilization of solid waste residues in non-ferrous metal smelting processes holds significant importance for achieving green and low-carbon development in the industry.The neutral leach residue from zinc hydrometallurgy contains multiple valuable metals,among which efficient recovery of indium is particularly critical.To address the issue of low indium leaching efficiency under conventional atmospheric pressure and low-acid conditions,this study systematically investigated the effects of acidity,reaction time,oxidative atmosphere,and reducing environment on indium leaching behavior using an atmospheric sulfuric acid leaching process with zinc smelting residue as the research object.Results indicate that under low-acid leaching conditions,indium leaching rate increases with elevated sulfuric acid concentration and prolonged reaction time.However,excessive oxidative atmosphere or extended reaction duration leads to a decrease in indium extraction efficiency.Under optimized conditions(85 g/L sulfuric acid concentration,liquid-to-solid ratio of 4∶1,leaching temperature of 85℃,reaction time of 5.5 hours,and 5 g/L zinc concentrate addition),the indium leaching rate reaches 60.87%.This study provides a feasible technological basis for recovering indium from zinc smelting residue under atmospheric pressure and low-acid conditions.
周晓龙;胡昌荣;何立秀;韦响
广西现代职业技术学院,广西 河池 547000广西现代职业技术学院,广西 河池 547000广西现代职业技术学院,广西 河池 547000广西现代职业技术学院,广西 河池 547000
锌冶炼中浸渣铟低酸浸出浸出率
zinc smeltingneutral leach residueindiumlow-acid leachingleaching rate
《福建冶金》 2026 (4)
16-19,4
2026年度广西科技界客库重点课题(桂科协[2026]P-112)
评论