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硝酸异丙酯含量对正庚烷激波诱导点火的影响OA

Influences of Isopropyl Nitrate Content on Ignition of n-Heptane Induced by Shock Waves

中文摘要英文摘要

为探究硝酸异丙酯(IPN)作为含能敏化剂对正庚烷(HP)激波诱导点火的促进作用,利用激波管实验平台,结合气动雾化与高速摄像技术,考察了IPN质量分数(0、10%、20%、30%)与入射激波压力(8 000、9 000、11 000 kPa)对HP激波诱导点火特性的影响.结果表明:在1 051~1 317 K范围内,纯HP未能点燃;IPN的添加显著缩短了点火延迟时间,且在9 000 kPa下,点火临界质量分数介于 10%~20%之间;IPN质量分数由 20%增至30%时,点火延迟时间缩短了约37.5%,火焰传播速度由2.75 mm/μs提升至3.57 mm/μs,提高了29.8%.提升激波强度同样促进点火,但效果随着IPN含量的增加而减弱,低含量IPN燃料对激波强度的变化更为敏感.揭示了IPN化学敏化与激波物理压缩在促进碳氢燃料点火中的协同机制,为极端条件下燃料的设计与燃烧调控提供了实验依据.

In order to understand the promoting effect of isopropyl nitrate(IPN)as an energetic sensitizer on shock wave induced ignition of n-heptane(HP),a shock tube experimental platform was used,combined with pneumatic atomi-zation and high-speed camera technology,to investigate the effects of IPN mass fraction(0,10%,20%,30%)and inci-dent shock wave pressure(8 000,9 000,11 000 kPa)on the shock wave induced ignition characteristics of HP.The re-sults show that the single-component HP fails to ignite at 1 051-1 317 K.The addition of IPN significantly reduces ignition delay time,and the critical mass fraction for ignition ranges from 10%to 20%at 9 000 kPa.When the mass fraction of IPN increases from20%to30%,the ignition delay time is shortened by about 37.5%,and the flame propagation speed increases from 2.75 mm/μs to 3.57 mm/μs,with an increase of 29.8%.Increasing the intensity of shock waves can also promote ignition,but the effect weakens with the increase of IPN.Fuels with low IPN content are more sensitive to changes in shock wave intensity.The synergistic mechanism of IPN chemical sensitization and shock wave physical compression in promoting ignition of hydrocarbon fuels was revealed,providing experimental basis for fuel design and combustion control under extreme conditions.

马善学;李建;唐琦;李亚宁;范源麟;郭祎嘉;王伯良

南京理工大学安全科学与工程学院(江苏 南京,210094)南京理工大学化学与化工学院(江苏 南京,210094)晋西工业集团有限责任公司(山西 太原,030027)南京理工大学化学与化工学院(江苏 南京,210094)南京理工大学化学与化工学院(江苏 南京,210094)南京理工大学安全科学与工程学院(江苏 南京,210094)南京理工大学化学与化工学院(江苏 南京,210094)

化学化工

燃料空气炸药硝酸异丙酯正庚烷气动雾化激波诱导点火

fuel-air explosiveisopropyl nitraten-heptanepneumatic atomizationignition induced by shock wave

《爆破器材》 2026 (3)

10-17,23,9

10.3969/j.issn.1001-8352.2026.03.002

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