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混装乳化炸药基质温度与敏化剂浓度匹配试验研究及应用OA

Experimental Study and Application on the Matching of Temperature and Sensitizer Concentration for Bulk Emulsion Explosive Matrix

中文摘要英文摘要

为解决现场混装乳化炸药在生产过程中因基质温度与敏化剂(亚硝酸钠)浓度不匹配所引起的炸药密度不均匀、爆破威力不稳定等问题,本研究系统探讨了基质温度与亚硝酸钠浓度之间的协同作用关系.通过采用正交试验设计方法,系统设置了40℃至70℃的基质温度梯度和1.2%至2.8%的亚硝酸钠浓度梯度,开展了多组对比试验,深入分析了两因素对乳化炸药密度影响的规律.试验结果显示:基质温度是影响发泡反应速率的关键因素,在较高温度条件下,反应速率显著加快,发泡过程更为迅速,但易造成过度发泡,导致炸药密度偏低;而在低温条件下,反应迟缓,发泡不充分,则易引起炸药密度偏高,影响爆破效果稳定性.同时,亚硝酸钠作为敏化剂,其浓度直接影响发泡效果与气泡结构稳定性,不同基质温度条件下均存在一个最佳浓度区间,以实现理想的炸药密度与爆轰性能.基于大量试验数据,本研究构建了适用于不同基质温度范围的亚硝酸钠配比指导表,明确了从低温至高温条件下对应的推荐敏化剂浓度,为现场操作提供了量化依据.经现场应用验证,采用该匹配表及相关调控方法后,乳化炸药的密度控制精度显著提高,不仅提升了爆破能量释放的稳定性,也降低了因密度异常诱发的拒爆等安全隐患,从而全面优化了爆破效果与作业安全性.本研究成果对提升现场混装炸药的质量控制水平、实现爆破性能的系统优化具有重要的理论指导与实践应用价值.

This study systematically investigated the synergistic relationship between matrix temperature and so-dium nitrite concentration to resolve density unevenness and explosive power instability in site-mixed emulsion explo-sives caused by the mismatch between matrix temperature and sensitizer(sodium nitrite)concentration during pro-duction.Using an orthogonal experimental design,matrix temperature gradients ranging from 40℃ to 70℃ and sodi-um nitrite concentration gradients ranging from 1.2%to 2.8%were systematically established.Multiple sets of com-parative tests were conducted to comprehensively examine the impact of these two factors on the density of emulsion explosives.The experimental results demonstrate that matrix temperature plays a critical role in determining the foa-ming reaction rate,with elevated temperatures markedly accelerating the reaction and,consequently,the foaming process.However,this acceleration often leads to excessive foaming,consequently reducing the explosive density.In contrast,lower temperatures slow the reaction,often resulting in insufficient foaming,which increases explosive densi-ty and adversely affects blasting stability.Additionally,the concentration of sodium nitrite,acting as the sensitizer,di-rectly influences both the foaming efficiency and the structural stability of the bubbles.For different matrix tempera-tures,there is an optimal concentration range to achieve ideal explosive density and detonation performance.Based on comprehensive experimental data,this study developed practical guidelines for sodium nitrite proportions across vari-ous matrix temperature ranges.These guidelines explicitly recommended specific sensitizer concentrations for low-to high-temperature conditions,providing quantitative references for field applications.Field validation confirmed that implementing this matching table and associated control techniques substantially enhanced the accuracy of emulsified explosive density regulation.This improvement not only boosted the effective release of explosive energy but also miti-gated safety risks,including density-related misfires,resulting in overall optimization of both blasting performance and operational safety.This study's findings offer valuable theoretical insights and practical applications for enhancing quality control in field-mixed explosives and systematically improving blasting performance.

陈运成;管伟明;杨志勇;赵明生;颜世留;李铁龙;侯得峰

宏大爆破工程集团有限责任公司,广州 510000新疆大学,乌鲁木齐 830017新疆天池能源有限责任公司,昌吉 831700宏大爆破工程集团有限责任公司,广州 510000宏大爆破工程集团有限责任公司,广州 510000宏大爆破工程集团有限责任公司,广州 510000新疆天池能源有限责任公司,昌吉 831700

矿业与冶金

混装乳化炸药基质温度敏化剂浓度密度控制

bulk emulsion explosivematrix temperaturesensitizer concentrationdensity control

《爆破》 2026 (2)

245-252,8

地球深部探测与矿产资源勘查国家科技重大专项基金资助项目(2024ZD1003406)非煤露天矿山安全智能开采国家矿山安全监察局重点实验室开放课题基金资助项目(2024-K03、2024-K05) National Major Science and Technology Project for Deep Earth Exploration and Mineral Resources Exploration(2024ZD1003406),Open Fund Project of the National Mine Safety Administration Key Laboratory for Safe and Intelligent Mining of Non-coal Open-pit Mines(2024-K03,2024-K05)

10.3963/j.issn.1001-487X.2026.02.026

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