首页|期刊导航|安全、健康和环境|基于动态模拟的甲苯一段硝化反应装置风险分析

基于动态模拟的甲苯一段硝化反应装置风险分析OA

Risk Analysis of Toluene First-Stage Nitrification Reactor Based on Dynamic Simulation

中文摘要英文摘要

针对传统风险评估方法严重依赖专家经验,难以评估动态工况引发的潜在事故风险,以国内某化工厂甲苯硝化核心反应单元为研究对象,依托 Aspen 流程模拟软件,开展甲苯硝化反应单元的稳态参数优化、动态工况模拟、过程控制特性分析及量化风险评估.此外,以反应物料流速波动、冷却介质失效3 类典型工艺偏差为核心研究场景,在危险与可操作性分析(Hazard and Operability Analysis,HAZOP)中引入定量偏差,通过仿真获取最大温升和到达最大温升所需时间,将动态响应的结果量化为事故发生的可能性和严重性,结合风险评价标准确定各场景风险等级.结果表明,冷却介质工况是影响甲苯硝化反应安全的关键参数,所构建的定量动态 HAZOP 分析方法可为化工企业动态安全管控、工艺参数优化、安全资源精准配置提供参考.

Traditional risk assessment methods heavily rely on expert experience and struggle to evaluate po-tential accident risks triggered by dynamic operating conditions.To address this limitation,the core toluene ni-tration reaction unit of a domestic chemical plant was selected as the research object.Using Aspen process simu-lation software,steady-state parameter optimization,dynamic simulation,process control characteristic analysis,and quantitative risk assessment were conducted for this reaction unit.Furthermore,focusing on three typical process deviations-such as fluctuations in reactant flow rates and cooling medium failure-quantitative deviations were introduced into the Hazard and Operability(HAZOP)analysis.The maximum temperature rise and the time required to reach it were obtained through simulation.These dynamic response results were then quantified into the likelihood and severity of accidents,and the risk levels of each scenario were determined based on es-tablished risk evaluation criteria.The results indicate that the cooling medium condition is the critical parameter affecting the safety of the toluene nitration reaction.The developed quantitative dynamic HAZOP analysis meth-od can provide a valuable reference for dynamic safety management,process parameter optimization,and the precise allocation of safety resources in chemical enterprises.

黄嘉璐

化学品安全全国重点实验室,山东 青岛 266104||中石化安全工程研究院有限公司,山东 青岛 266104||中石化国家石化项目风险评估技术中心有限公司,山东 青岛 266104

化学化工

动态模拟甲苯硝化风险量化HAZOPAspen流程模拟

dynamic simulationtoluene nitration reaction unitquantitative risk assessmentHAZOPAspen process simulation

《安全、健康和环境》 2026 (6)

21-27,87,8

10.3969/j.issn.1672-7932.2026.06.003

评论