首页|期刊导航|铜业工程|铜冶炼渣中铜、铁高效回收技术研究进展

铜冶炼渣中铜、铁高效回收技术研究进展OA

Technology Development for Efficient Recovery of Copper and Iron from Copper Smelting Slag

中文摘要英文摘要

铜冶炼渣作为火法炼铜工艺中产生的主要固体废弃物,含有丰富的铜(0.5%~4.6%)和铁(30%~49%),是具有重要回收价值的二次资源.然而,全球超过80%的铜渣仍采用堆存方式处置,既占用土地资源,又因铅、砷等有毒元素迁移释放而造成环境威胁.实现铜渣中铜、铁的高效回收,对保障资源安全和推动有色金属行业绿色转型具有重要意义.本文系统梳理了铜冶炼渣的物化特性与矿物学特征,深入分析了浮选、火法冶金(还原焙烧-磁选、熔融还原、氧化焙烧-磁选)、湿法浸出(化学浸出、微生物浸出)及联合工艺的技术原理与研究现状.面对当前铜铁分离效率低、铁资源回收率不高、二次渣难以全质化利用等共性挑战,未来研究可聚焦于铜铁协同提取机理、低碳强化技术,以及全组分梯级利用等方向,为铜冶炼渣的资源化、无害化与高值化利用提供理论支撑.

Copper smelting slag,the primary solid waste generated from pyrometallurgical copper production,is rich in valuable metals such as Cu(0.5%~4.6%)and Fe(30%~49%),making it a significant secondary resource for recovery.However,over 80%of the global copper slag is still disposed of by stockpiling,which not only occupies land resources but also poses environmental threats due to the migration and release of toxic elements like Pb and As.Efficient recovery of copper and iron from copper slag is therefore of great significance for ensuring resource security and promoting the green transformation of the nonferrous metals industry.This paper systematically reviewed physicochemical properties and mineralogical characteristics of copper smelting slag,and provided an in-depth analysis of technical principles and research status of various processes,including flotation,pyrometallurgy(reducing roasting-magnetic separation,smelting reduction,oxidizing roasting-magnetic separation),hydrometallurgy(chemical leaching,bioleaching),and combined processes.Current technologies still face common challenges such as low copper-iron separation efficiency,low iron recovery rate,and difficulties in the full-component utilization of secondary slag.On this basis,future research is prospected to focus on the synergistic extraction mechanisms of copper and iron,low-carbon intensification technologies,and stepwise utilization of full components,aiming to provide theoretical support for resources utilization,detoxification,and high-value utilization of copper smelting slag.

高云川;马士淋;符海桃;李祥;宋强;童雄;谢贤;张文杰

云南华联锌铟股份有限公司,云南 文山 663701||昆明理工大学 国土资源工程学院,云南 昆明 650031云南锡铟实验室有限公司,云南 昆明 650200云南华联锌铟股份有限公司,云南 文山 663701||昆明理工大学 国土资源工程学院,云南 昆明 650031昆明理工大学 国土资源工程学院,云南 昆明 650031云南锡铟实验室有限公司,云南 昆明 650200||昆明理工大学 国土资源工程学院,云南 昆明 650031昆明理工大学 国土资源工程学院,云南 昆明 650031昆明理工大学 国土资源工程学院,云南 昆明 650031昆明冶金研究院有限公司,云南 昆明 650021

矿业与冶金

铜冶炼渣铁回收浸出浮选磁选

copper smelting slagiron recoveryleachingflotationmagnetic separation

《铜业工程》 2026 (3)

1-13,13

国家自然科学基金(52364031)云南锡铟实验室开放课题(202405AR340002-25EA01)深地国家科技重大专项(2024ZD1004006)

10.3969/j.issn.1009-3842.2026.03.001

评论