二氧化碳矿化养护加气混凝体砌块性能影响因素模型构建及分析研究OA
Construction and analysis of influence factor model on properties of aerated concrete blocks cured by carbon dioxide mineralization
为实现燃煤固废和CO2资源化利用,本文以煤电固废为主要原料制备加气混凝土砌块.采用基于多目标优化的响应曲面法构建加气混凝土固碳率、抗压强度与养护温度、养护时间、养护压力的数值模型,并对模型可靠性和适应性进行校验.结果表明:CO2矿化养护的主要产物为碳酸钙,随着养护压力升高,碳酸钙晶体的粒径增大,产物界面出现细微裂缝;随着养护温度升高,混凝土中的惰性莫来石组分开始参与反应,碳酸钙结晶度更高,产物界面更加致密.矿化产物可填充加气混凝土的纳米级孔隙,有助于改善其力学性能.当养护压力为0.1 MPa、养护温度为65℃、养护时间为2 h时,其7 d抗压强度为3.53 MPa,较自然养护提高35.8%.性能预测模型表明,当养护压力0.53 MPa、养护温度56.5℃、养护时间119 min时,加气混凝土可获得最优抗压强度和较高固碳率,分别为3.69 MPa和8.4%;试验测量值分别为3.63 MPa和8.22%,相对误差仅为1.6%、2.1%,说明模型具有较好的可靠性和适应性.
To achieve the resource utilization of coal-fired solid waste and carbon dioxide,aerated concrete blocks were prepared using coal power solid wastes as the main raw materials in this paper.A numerical model of the carbon sequestration rate and compressive strength of the aerated concrete in relation to curing temperature,curing time,and curing pressure was constructed based on a multi-objective optimization response surface method,and the reliability and applicability of the model were verified.The results show that calcium carbonate is the main product of CO2 mineralisation curing.Increasing curing pressure enlarges the particle size of calcium carbonate crystals and induces microcracks at product interfaces;as curing temperature rises,the inert mullite in concrete begins to participate in reactions,yielding calcium carbonate with higher crystallinity and denser product interfaces.Mineralized products can fill nanoscale pores inside aerated concrete,effectively improving its mechanical properties.When the curing pressure was 0.1 MPa,temperature was 65℃ and duration was 2 hours,the 7-day compressive strength reaches 3.53 MPa,rising by 35.8% compared with natural curing.The performance prediction model reveals that the aerated concrete achieves the optimal comprehensive performance with the maximum compressive strength and relatively high carbon sequestration rate at curing pressure of 0.53 MPa,temperature of 56.5℃ and curing time of 119 minutes,with corresponding theoretical values of 3.69 MPa and 8.4%.The actual measured values are 3.63 MPa and 8.22%,with relative errors of 1.6% and 2.1% respectively,proving the favorable reliability and adaptability of the established model.
李亚芳;曹俊灏;林建安;罗旷;易臻伟;王涛;王兴琦
浙江大学能源工程学院,浙江 杭州 310058广东粤电靖海发电有限公司,广东 揭阳 515200广东粤电靖海发电有限公司,广东 揭阳 515200浙江大学能源工程学院,浙江 杭州 310058浙江大学能源工程学院,浙江 杭州 310058浙江大学能源工程学院,浙江 杭州 310058清捕零碳(杭州)科技有限公司,浙江 杭州 100200
建筑与水利
二氧化碳矿化加气混凝土响应曲面法固碳率
carbon dioxide mineralisationaerated concreteresponse surface methodologycarbon sequestration rate
《能源工程》 2026 (3)
57-66,10
宁夏回族自治区重点研发项目(2024BEE02041)
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