多元卤化盐高温相变热储能研究与应用试验OA
Research and application experiment on high temperature phase change thermal energy storage of multicomponent halogenated salts
高温热储能是一种能够为电网实现削峰填谷的大规模储能方式,其储存的热能品位高,热机转换效率(即卡诺循环效率)优异.本文研究了作为高温热储能材料的多元卤化盐热物理性能,及其在高温工况下与碳钢材料的相容特性,指出多元卤化盐用于高温相变热储能时,需要解决熔盐封装方法、储能加热方式、储能系统释热结构设计等技术问题,并对每个问题给出了具体的解决措施,最关键的是提出采用熔盐盒分散灌装熔盐并组成熔盐堆的技术方案,解决了工作温度高达750℃或800℃,且固液状态交替变化的熔盐工程化应用的封装问题.根据研究内容,构思了将多元卤化盐高温相变热储能技术进行工程化应用的试验方案,并按试验方案搭建试验装置,进行通电加热储能和通水产汽释热试验.试验结果表明:多元卤化盐相变热储能可满足高温热储能的性能要求,具有储能温度高、储能密度大、储能系统结构紧凑、操作方法简单,并且从试验过程和试验结果可以看到,采用熔盐盒分散灌装熔盐,是比较合适高温卤化盐的封装方法.本研究项目以及试验装置和试验结果,可以为熔盐高温相变热储能技术的工程化应用提供参考.
High-temperature thermal energy storage is a large-scale energy storage method capable of implementing peak shaving and valley filling for the power grid,its stored thermal energy grade is high,and the conversion efficiency of thermal engine(i.e.Carnot cycle efficiency)is high.The thermophysical properties of multicomponent halogenated salt as high temperature thermal energy storage material and its compatibility with carbon steel at high temperature were studied,the technical problems of molten salt packaging method,energy storage and heating method,discharge structure design of energy storage system and other technical problems that need to be solved when multicomponent halogenated salts is used for high temperature phase change thermal energy storage are pointed out,specific solutions are proposed for each problem,the most critical is to put forward the technical scheme of dispersedly filling molten salt with molten salt box to form molten salt pile,solved the packaging problem for engineering applications of molten salts with temperatures up to 750℃or 800℃and alternating solid-liquid states.Based on the research contents,a test scheme for engineering application of high temperature phase change thermal energy storage technology of multicomponent halide salt is conceived,a set of test device is built according to the test scheme,and then conduct the test of heating by powering on storing heat and introduce water to generate steam to release heat,the experimental results indicate that,the multicomponent halide salts phase change thermal energy storage meets the performance requirements of high-temperature thermal energy storage,high energy storage temperature and high energy storage density,the energy storage system has a compact structure,the operation method is simple and easy,and from the experimental process and results,it can be seen that,using a molten salt box for dispersed filling of molten salt,for high-temperature halide salts,it is a suitable packaging method.This research project,along with the experimental setup and results,can provide reference for the engineering application of high-temperature phase change thermal energy storage technology using molten salt.
倪永良;董旭;刘华明;李建山;倪平;王叔范
扬州大学扬州碳中和技术创新研究中心,江苏 扬州 225127||江苏攀登能源科技有限公司,江苏 无锡 214400||江苏省化工设备制造安装有限公司,江苏 常州 213000扬州大学扬州碳中和技术创新研究中心,江苏 扬州 225127江苏攀登能源科技有限公司,江苏 无锡 214400江苏华东炉业有限公司,江苏 镇江 212300张家港市兆丰昌盛金属制品厂,江苏 苏州 215600江苏省化工设备制造安装有限公司,江苏 常州 213000
能源科技
熔盐相变储能卤化盐热能品位卡诺循环效率高温储能超临界机组储能试验装置
molten salt phase-change energy storagehalogenated saltthermal energy gradecarnot cycle efficiencyhigh temperature energy storagesupercritical unitenergy storage test device
《能源工程》 2026 (3)
17-25,9
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