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AP/HMX质量比对NEPE推进剂燃烧性能影响OA

Influence of AP/HMX Mass Ratio on Combustion Performance of NEPE Propellant

中文摘要英文摘要

为了探究高氯酸铵(AP)与奥克托今(HMX)质量比对硝酸酯增塑聚醚(NEPE)推进剂燃烧性能的影响机制,本研究采用水下声发射法、微热电偶、同轴数字全息、凝聚相产物收集法等多种手段,系统研究了AP/HMX质量比(13/50~19/44)对NEPE推进剂燃速、燃烧波结构、凝聚相产物特性的影响规律.结果表明,随AP/HMX质量比增加,推进剂燃速由11.4 mm·s-1增至12.3 mm·s-1,爆热由6820 kJ·kg-1提升至7107 kJ·kg-1,凝相预热区厚度由317.3 μm减小至183.6 μm,燃面温度由336℃升高至494℃,气相火焰区最高温度由2934℃增至3017℃,铝凝团中值粒径由275.86 μm减小至209.77 μm,凝聚相产物活性铝含量由2.55%降至0.86%.可通过改变AP/HMX质量比,利用热力学与动力学协同作用调控NEPE推进剂燃烧性能.

To elucidate the influence mechanism of the mass ratio of ammonium perchlorate(AP)to octogen(HMX)on the combustion performance of nitrate ester plasticized polyether(NEPE)propellants,multiple testing methods including the under-water acoustic emission method,micro-thermocouple technique,coaxial digital holography and condensed-phase product col-lection method were adopted in this study.The effects of AP/HMX mass ratio(13/50-19/44)on the burning rate,combustion wave structure and condensed-phase product characteristics of NEPE propellants were systematically investigated.The results show that with the increase of AP/HMX mass ratio,the burning rate of propellants increases from 11.4 mm·s-1 to 12.3 mm·s-1,the explosion heat rises from 6820 kJ·kg-1 to 7107 kJ·kg-1,the thickness of condensed-phase preheating zone decreases from 317.3 μm to 183.6 μm,the burning surface temperature rises from 336℃to 494℃,the maximum temperature of gas-phase flame zone increases from 2934℃to 3017℃,the median diameter of aluminum agglomerates decreases from 275.86 μm to 209.77 μm,and the active aluminum content in condensed-phase products decreases from 2.55%to 0.86%.The combustion performance of NEPE propellants can be regulated by adjusting the AP/HMX mass ratio via the synergistic action of thermody-namics and kinetics.

常亚蒙;曾绮卉;蒲旸;王鼎程;陈玉坤;李春涛;王芳;李伟

航天化学能源全国重点实验室,湖北 襄阳 441003||湖北航天化学技术研究所,湖北 襄阳 441003航天化学能源全国重点实验室,湖北 襄阳 441003||湖北航天化学技术研究所,湖北 襄阳 441003航天化学能源全国重点实验室,湖北 襄阳 441003||湖北航天化学技术研究所,湖北 襄阳 441003航天化学能源全国重点实验室,湖北 襄阳 441003||湖北航天化学技术研究所,湖北 襄阳 441003航天化学能源全国重点实验室,湖北 襄阳 441003||湖北航天化学技术研究所,湖北 襄阳 441003航天化学能源全国重点实验室,湖北 襄阳 441003||湖北航天化学技术研究所,湖北 襄阳 441003航天化学能源全国重点实验室,湖北 襄阳 441003||湖北航天化学技术研究所,湖北 襄阳 441003航天化学能源全国重点实验室,湖北 襄阳 441003||湖北航天化学技术研究所,湖北 襄阳 441003

军事科技

NEPE推进剂高氯酸铵(AP)/奥克托今(HMX)质量比铝团聚燃烧性能

NEPE propellantmass ratio of AP/HMXaluminum agglomerationcombustion performance

《含能材料》 2026 (6)

674-683,10

10.11943/CJEM2026049

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