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机械力促进的光化学反应在有机合成中的应用介绍OA

Mechanochemically Promoted Photochemical Reactions in Organic Synthesis

中文摘要英文摘要

机械化学合成是一种利用研磨、剪切等机械能输入方式促进合成反应的实施手段,具有绿色环保、高效节能等显著优势.近年来,机械力与光化学的协同作用逐渐成为研究热点.通过交错或同步进行机械研磨与光照操作,可实现二者的优势互补.本文系统性综述了机械力驱动光化学反应的原理、装置及研究进展.这些创新方法不仅有效拓展了机械化学的应用边界,还推动了有机合成、纳米材料制备等领域的绿色转型.未来,机械光化学有望在药物开发、能源存储及可持续合成等领域发挥关键作用,并为多学科交叉研究提供新的思路.该介绍有助于拓宽学生对不同化学领域的认知,加深对化学反应本质的理解,提升学习兴趣,并激发探索未知的好奇心.

Mechanochemical synthesis is an approach that utilizes mechanical energy input,such as grinding and shearing,to promote synthetic reactions,offering notable advantages in terms of environmental sustainability,high efficiency,and energy savings.In recent years,the synergistic interaction between mechanical force and photochemistry has emerged as a research hotspot.By alternating or synchronizing mechanical grinding with light irradiation,the complementary advantages of both techniques can be effectively harnessed.This review systematically summarizes the principles,apparatus,and recent advances in mechanochemically driven photochemical reactions.These innovative methodologies not only expand the application scope of mechanochemistry but also contribute to the green transformation of fields such as organic synthesis and nanomaterial fabrication.Looking ahead,mechanophotochemistry is expected to play a pivotal role in drug development,energy storage,and sustainable synthesis,while also providing new insights for interdisciplinary research.Moreover,this review can help broaden students'understanding of various chemical disciplines,deepen their comprehension of fundamental reaction mechanisms,enhance their interest in chemistry,and inspire curiosity for exploring the unknown.

唐琪浩;信晓华;王云侠;王晗

西北大学化学与材料科学学院,陕西 西安 710127西北大学化学与材料科学学院,陕西 西安 710127西北大学化学与材料科学学院,陕西 西安 710127西北大学化学与材料科学学院,陕西 西安 710127

社会科学

机械化学光化学反应球磨技术绿色合成

MechanochemistryPhotochemical ReactionBall Milling TechnologyGreen Synthesis

《大学化学》 2026 (6)

321-327,7

西北大学2023年本科人才培养建设项目陕西省一流本科课程-有机化学建设项目西北大学2024年本科人才培养建设项目(JX2024031)国家自然科学基金项目(22579138)

10.12461/PKU.DXHX202503131

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