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气体-应变双模态柔性应变传感器的制备及其应用OA

Preparation and application of gas-strain dual-mode flexible strain sensor

中文摘要英文摘要

针对传统柔性传感器单一模态传感的局限性,研究采用光学-电学信号分离策略,旨在开发一种兼具气体检测和应变传感功能的双模态柔性一维传感器.通过四苯基乙烯(TPE)掺杂热塑性聚氨酯(TPU)制备的气敏纤维与经盐酸多巴胺(PDA)修饰并负载聚吡咯(PPy)的聚苯乙烯-丁二烯-苯乙烯(SBS/PDA/PPy)导电纤维结合,采用包缠纱结构设计,制备了TPU/SBS柔性应变传感器.实验结果表明,该传感器在气体检测方面,传感器对四氢呋喃气体的最低检测限为59.4 mL/m3,荧光猝灭效率达78.3%,且具有优异的可逆性和稳定性.在应变传感方面,传感器具有0%~60%的传感范围,灵敏系数达30.455,响应时间为167 ms,循环稳定性超过1000次.可穿戴性能测试表明,该传感器能够实时监测人体关节运动和呼吸变化,输出信号稳定.研究为多功能集成柔性传感器的开发提供了新思路,适用于高危有机气体作业环境中的行为检测与气体浓度预警.

This study presents a novel dual-modal flexible sensor that employs an optical-electrical signal decoupling strategy to achieve strain and gas detection,thereby overcoming the limitations of conventional single-modal flexible sensors.The device is constructed using a wrapped-yarn structure,in which polystyrene-butadiene-styrene(SBS)conductive fibers modified with dopamine hydrochloride and polypyrrole(SBS/PDA/PPy)function as the core strain-sensing component,wrapped with tetraphenylethylene-doped thermoplastic polyurethane(TPE-TPU)fibers serve as the gas-responsive component.Experimental results demonstrate that,for gas sensing,the sensor achieves a low detection limit of 59.4 mL/m3 for tetrahydrofuran(THF),along with a fluorescence quenching efficiency of 78.3%and excellent reversibility and stability.For strain sensing,the device exhibits a broad detection range of 0%-60%,a high gauge factor of 30.455,a rapid response time of 167 ms,and remarkable cycling durability exceeding 1000 cycles.Wearable tests further validate its reliable performance in monitoring human joint motion and respiratory activity.Overall,this work provides a robust strategy for developing multifunctional flexible sensors and demonstrates significant potential for applications in human behavior monitoring and early warning of volatile organic compound gas concentrations in high-risk environments.

周志娟;张晨超;徐慧慧;袁小红;王清清

江南大学 生态纺织教育部重点实验室,江苏 无锡 214122江南大学 生态纺织教育部重点实验室,江苏 无锡 214122江南大学 生态纺织教育部重点实验室,江苏 无锡 214122闽江学院 服装与艺术工程学院,福州 350108江南大学 生态纺织教育部重点实验室,江苏 无锡 214122

通用工业技术

双模态响应荧光可视化应变传感气体传感包缠结构

dual-modal responsefluorescence visualizationstrain sensinggas sensingwrapped structure

《材料工程》 2026 (6)

85-96,12

福州市科技计划项目(2024-ZD-006)

10.11868/j.issn.1001-4381.2025.000457

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