Al-Ce-Ni-Cu合金的微观组织与室温和高温性能研究OA
Study on the Microstructure and Room-and High-temperature Properties of Al-Ce-Ni-Cu Alloy
Al-Ce基合金具有低密度、优异的抗粗化性能和良好的铸造性能,是200~450 ℃范围内具有稳定服役能力的潜在材料.本文制备了成分为Al-10%Ce-5%Ni-4%Cu(质量分数,简称ACNC)的合金,系统研究了其在铸态及等温时效过程中的显微组织演变,测试了其在室温和高温下的拉伸性能,并探讨了相关强化机制.结果表明,ACNC合金呈现亚共晶组织,由初生α-Al枝晶、"长条状或梅花状"的Al3Ni相、"鱼骨状"的Al11(Ce,Cu)3相以及共晶团组成.共晶团内Al3CeCu与Al3Ni相以纤维状相互缠结.在450 ℃等温时效24 h后,共晶相缓慢粗化,其宽度从(154±64)nm增至(519±241)nm,间距从(380±155)nm增至(1 029±511)nm,合金硬度随之逐渐下降.而在590 ℃过时效5 h后,Al3Ni与Al3CeCu相迅速球化,导致硬度急剧降低.合金在室温、200、300和400 ℃下的屈服强度分别为(136±7)MPa、(121±2)MPa、(86±1)MPa 和(45±2)MPa.
Al-Ce-based alloys,characterized by low density,excellent coarsening resistance and good castability,are promising materials for stable service in the temperature range of 200~450℃.In this study,an alloy with a nominal composition of Al-10Ce-5Ni-4Cu(wt.%,named ACNC)was prepared.The microstructure evolution in the as-cast sample and during isothermal aging was systematically investigated,and its tensile properties at room and elevated temperatures were tested,along with the underlying strengthening mechanisms.The results indicate that the ACNC alloy has a hypoeutectic microstructure,consisting of primary α-Al dendrites,"rod-like or plum-blossom-like"Al3Ni phases,"fishbone-like"Al11(Ce,Cu)3 phases,and eutectic colonies.Within the eutectic colonies,the Al3CeCu and Al3Ni phases are entangled in a fibrous manner.After isothermal aging at 450℃ for 24 h,the width of the eutectic phases increase from(154±64)nm to(519±241)nm,and the eutectic spacing expandes from(380±155)nm to(1 029±511)nm,accompanied by a progressive decrease in hardness.In contrast,severe overaging at 590℃ for 5 h leads to rapid spheroidization of the Al3Ni and Al3CeCu phases,resulting in a sharp decrease in hardness.The yield strengths of the alloy at room temperature,200,300 and 400℃ are measured as(136±7)MPa,(121±2)MPa,(86±1)MPa,and(45±2)MPa,respectively.
刘敬彬;高通;刘相法
山东大学材料液固结构演变与加工教育部重点实验室,山东济南 250061山东大学材料液固结构演变与加工教育部重点实验室,山东济南 250061山东大学材料液固结构演变与加工教育部重点实验室,山东济南 250061
矿业与冶金
Al-Ce-Ni-Cu合金高温共晶显微组织
Al-Ce-Ni-Cu alloyelevated-temperatureeutecticmicrostructure
《铸造技术》 2026 (5)
489-497,9
国家自然科学基金面上项目(52471040)
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