首页|期刊导航|铸造|光固化增材制造精铸用陶瓷过滤网的高固含量浆料设计及性能研究

光固化增材制造精铸用陶瓷过滤网的高固含量浆料设计及性能研究OA

Research on the Design and Properties of High-Solid-Loading Slurries for Ceramic Filters via Stereolithography for Investment Casting

中文摘要英文摘要

高性能陶瓷过滤网对航空发动机与燃气轮机高温合金精密铸造至关重要,但其传统制备工艺在实现可定制化孔隙结构方面存在局限,而光固化增材制造技术为实现高精度、可定制化的陶瓷过滤网制备提供了新的技术途径.在此制备工艺中,陶瓷浆料的固含量是决定烧结体致密度、尺寸稳定性及最终力学性能的核心因素.本研究系统探究了树脂体系与颗粒级配两大关键材料因素对高固含量浆料性能的协同调控机制.结果表明:通过调节低粘度阳离子树脂(TMPO)的比例,可有效降低体系粘度,从而为引入更高比例的陶瓷固相创造条件;同时,优化粗细颗粒级配(500 nm与1 μm)能够利用细颗粒填充粗颗粒间隙,显著提高颗粒堆积密度与固相负载量,是实现高固含量浆料的关键途径.基于上述机理,通过材料粒径配比与打印工艺的协同优化,最终成功制备出固含量55vol.%的浆料,并最终得到高精度的孔隙结构(体积密度3.61 g/cm3,开孔隙率1.35%)、力学性能优异(室温与高温弯曲强度分别为263.67 MPa和17.68 MPa)的陶瓷过滤网.本研究为光固化增材制造陶瓷过滤网设计了高固含量、高性能的陶瓷浆料,实现了复杂孔隙结构可控的陶瓷过滤网制备.

High-performance ceramic filters are crucial for the precision casting of superalloys used in aero-engines and gas turbines.However,traditional fabrication processes face limitations in achieving complex and precise porous structures.Stereolithography-based additive manufacturing offers a novel technological pathway for producing ceramic filters with high precision and customizability.In this method,the solid loading of the ceramic slurry is the core factor determining the sintered body's density,dimensional stability,and final mechanical properties.Therefore,this study systematically investigates the synergistic regulation mechanism of two key material factors—the resin system and particle gradation—on the performance of high-solid-loading slurries.The results indicate that adjusting the proportion of low-viscosity cationic resin(TMPO)can effectively reduce the system viscosity,thereby providing conditions for introducing a higher proportion of ceramic solid phases.Simultaneously,optimizing the gradation of coarse and fine particles(500 nm and 1 μm)enables fine particles to fill the gaps between coarse particles,significantly improving particle packing density and solid loading,which is a key approach to achieving high-solid-loading slurries.Based on the above mechanisms,through the synergistic optimization of material particle size distribution and printing parameters,a slurry with 55vol.%solid loading was successfully prepared.This ultimately yielded a ceramic filter mesh with high-precision pore structure(bulk density of 3.61 g/cm3,open porosity of 1.35%)and excellent mechanical properties(room-temperature and high-temperature flexural strengths of 263.67 MPa and 17.68 MPa,respectively).This research designs a high-solid-loading,high-performance ceramic slurry for stereolithography-based additive manufacturing of ceramic filter meshes,enabling the fabrication of ceramic filters with controllable complex pore structures.

张婷婷;李乔磊;于孟阳;纪帅;梁静静;PAOLO Colombo;李金国

中国科学院金属研究所,辽宁 沈阳 110016中国科学院金属研究所,辽宁 沈阳 110016||意大利帕多瓦大学工业工程系,意大利帕多瓦 35131博环新材料科技(辽宁)有限公司,辽宁 沈阳 110021博环新材料科技(辽宁)有限公司,辽宁 沈阳 110021中国科学院金属研究所,辽宁 沈阳 110016意大利帕多瓦大学工业工程系,意大利帕多瓦 35131||美国宾夕法尼亚州立大学材料科学与工程系,美国宾夕法尼亚 16802中国科学院金属研究所,辽宁 沈阳 110016

化学化工

陶瓷过滤网增材制造浆料精密铸造陶瓷辅材颗粒级配力学性能

ceramic filteradditive manufacturingslurryprecision castingceramic auxiliary materialsparticle gradationmechanical property

《铸造》 2026 (6)

587-594,8

国家自然科学基金(52402094)博环新材料科技(辽宁)有限公司企业横向项目(技合2025-181号).

10.27014/j.cnki.zhuzao.2026.0078

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