临氢爆破片用超高纯316L不锈钢材料洁净度研究OA
Research on the cleanliness of ultra-high purity 316L stainless steel material for hydrogen pressure rupture discs
针对将扩展应用于高压储氢容器临氢爆破片安全泄放装置的超高纯(UHP)AISI 316L奥氏体不锈钢,其内部夹杂物作为氢陷阱和腐蚀萌生源,将直接影响材料的氢脆敏感性与爆破片的起爆精度及可靠性,而当前行业对其洁净度与夹杂物控制缺乏系统评价与比较的现状.本研究通过对比国内外不同厂商采用真空感应熔炼联合真空自耗重熔(A料),以及氩氧脱碳炉结合VAR工艺(B料)制备的材料,开展了系统性质量评估.创新性地综合运用金相显微镜、扫描电子显微镜与能谱分析等微观表征手段,并结合热力学计算软件模拟冷却过程中夹杂物的演变,揭示了不同工艺与来源材料的夹杂物特征与分布规律.研究结果表明,在参与评测的样品中,中国甲厂生产的B料具有最优异的洁净度,其夹杂物密度和面积分数均显著低于其他样品.该结果与热力学模拟预测高度一致,证实了所采用方法的可靠性.研究结果为超高纯316L不锈钢在关键临氢爆破片安全部件中的选用与工艺优化提供了重要依据,也为同类高洁净度材料的质量评价与控制提供了可参考的分析思路和方法支持.
This study focuses on the application of expansion technology to rupture disc safety relief devices for high-pressure hydrogen storage vessels,using ultra-high purity(UHP)AISI 316L austenitic stainless steel.Internal inclusions act as hydrogen traps and corrosion initiation sites,directly influencing the material's susceptibility to hydrogen embrittlement as well as the triggering accuracy and reliability of the rupture disc.Currently,the industry lacks a systematic evaluation and comparison of cleanliness and inclusion control for such materials.In this study,a systematic quality assessment was carried out by comparing materials produced by different manufacturers using vacuum induction melting combined with vacuum arc remelting(Material A),as well as the argon-oxygen decarburization process followed by VAR(Material B).Innovatively,this study employed a combination of microscopic characterization techniques including metallographic microscopy,scanning electron microscopy,and energy-dispersive X-ray spectroscopy,coupled with thermodynamic calculations to simulate the evolution of inclusions during cooling.This approach revealed the characteristics and distribution patterns of inclusions resulting from different processes and sources.The results indicate that among the evaluated samples,Material B produced by China Factory A exhibited the best cleanliness,with both inclusion density and area fraction significantly lower than those of the other samples.This finding is in strong agreement with the thermodynamic simulation predictions,confirming the reliability of the adopted methodology.The results provide important guidance for the selection and process optimization of ultra-high purity 316L stainless steel used in critical hydrogen-containing rupture disc safety components,and also offer a reference framework for the quality assessment and control of similar high-cleanliness materials.
杨超;骆辉;周忠警;江一凡
中国特种设备检测研究院,北京 100029||嘉兴市长三角氢安全研究中心,浙江 嘉兴 314200||国家市场监督管理总局重点实验室(氢能储运装备安全),浙江 嘉兴 314200中国特种设备检测研究院,北京 100029||嘉兴市长三角氢安全研究中心,浙江 嘉兴 314200||国家市场监督管理总局重点实验室(氢能储运装备安全),浙江 嘉兴 314200嘉兴市长三角氢安全研究中心,浙江 嘉兴 314200||国家市场监督管理总局重点实验室(氢能储运装备安全),浙江 嘉兴 314200嘉兴市长三角氢安全研究中心,浙江 嘉兴 314200||国家市场监督管理总局重点实验室(氢能储运装备安全),浙江 嘉兴 314200
机械制造
超高纯316L不锈钢临氢爆破片非金属夹杂物洁净度
ultra-high purity 316L stainless steelhydrogen-resistant rupture discnon-metallic inclusionscleanliness level
《压力容器》 2026 (3)
15-24,10
国家重点研发计划(2021YFB4000803)国家市场监督管理总局科技计划项目(2024MK212)
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